Stereoselective and regioselective pinacol-type rearrangement of a fused bicyclic oxetanol scaffold
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.201701214
Abstract: The Paterno-Buchi reaction between benzaldehyde and trimethylsilyloxycyclopentene gave access to unprecedented silyl ether derivatives of 6-oxabicyclo[3.2.0]heptan-1-ol. These bicyclic structures underwent selective reductive ring opening as well as acid-catalysed pinacol-type rearrangement with complete regioselectivity, accompanied by… read more here.
Keywords: pinacol type; stereoselective regioselective; type rearrangement;