Articles with "pincer" as a keyword



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Instantaneous High‐Resolution Visual Imaging of Latent Fingerprints in Water Using Color‐Tunable AIE Pincer Complexes

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Published in 2022 at "Advanced Materials"

DOI: 10.1002/adma.202202540

Abstract: Instant visualization of latent fingerprints is developed by using a series of water‐soluble terpyridine zinc complexes as aggregation‐induced emission probes in pure water, under UV light or ambient sunlight. By simply soaking, or spraying with… read more here.

Keywords: pincer; color tunable; latent fingerprints; water ... See more keywords
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Single Iridium Pincer Complex for Roundtrip Electrochemical Conversion between Carbon Dioxide and Formate

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Published in 2019 at "ChemCatChem"

DOI: 10.1002/cctc.201900083

Abstract: An iridium (III) complex based on a PONOP pincer ligand (PONOP=2,6‐bis(di‐tert‐butylphosphinito)pyridine) is a versatile catalyst for both electro‐reduction of CO2 to formate and formate electro‐oxidation to CO2. The electro‐reduction of CO2 in acetonitrile is very… read more here.

Keywords: pincer; iridium; conversion; co2 ... See more keywords
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The Role of Monoanionic Aryl Pincer Ligands in the Stabilization of Group 14 Metallylenes

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Published in 2020 at "European Journal of Inorganic Chemistry"

DOI: 10.1002/ejic.202000409

Abstract: Pincer ligands have an important role in stabilizing group 14 metallylenes. The particular structure of the aryl pin-6 cer ligands makes them a unique ligand platform. This review is focused on presenting monoanionic metallylenes stabilized… read more here.

Keywords: pincer; pincer ligands; aryl pincer; role ... See more keywords
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Pincer‐type MRI morphology seen in over a third of asymptomatic healthy volunteers without femoroacetabular impingement

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Published in 2019 at "Journal of Magnetic Resonance Imaging"

DOI: 10.1002/jmri.26297

Abstract: In daily routine, pincer femoroacetabular impingement (FAI) findings are often seen without a clinical diagnosis of pincer FAI. read more here.

Keywords: pincer; femoroacetabular impingement; type mri; pincer type ... See more keywords
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Synthesis by Si-H bond lithiation of novel half-pincer and pincer silyllithium compounds and their molecular structures

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Published in 2017 at "Structural Chemistry"

DOI: 10.1007/s11224-017-0910-6

Abstract: The synthesis and the X-ray structural analysis of novel pincer and half-pincer silyllithiums: Ar2(N)(tBu2MeSi)SiLi (Ar(N) = o-dimethylbenzylamine) (2a), Ar2(N)(tBu)SiLi·Et2O (2b), Me2N(CH2)3(tBuMe2Si)2SiLi (4) and [Ar(N)(tBuMe2Si)2SiLi]4 (8) are presented. These silyllithiums were obtained by metalation of the corresponding silanes… read more here.

Keywords: pincer; pincer silyllithium; bond lithiation; synthesis bond ... See more keywords
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An important intermediate step in the evolution of pincer wasps: an extraordinary new type of chela from mid-Cretaceous Burmese amber (Hymenoptera, Dryinidae)

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Published in 2020 at "Cretaceous Research"

DOI: 10.1016/j.cretres.2020.104420

Abstract: Abstract Raptodryinus patrickmuelleri gen. et sp. nov., that belongs to Raptodryininae subfam. nov. (Hymenoptera: Dryinidae), is described from Burmese amber. Raptodryininae subfam. nov. represents one of the first fossil groups of chelate dryinids, documenting the… read more here.

Keywords: chela; pincer; evolution; pincer wasps ... See more keywords
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Free methylidyne? CCC-NHC tantalum bis(imido) reactivity: protonation, rearrangement to a mixed unsymmetrical CCC-N-heterocyclic carbene/N-heterocyclic dicarbene (CCC-NHC/NHDC) pincer tantalum bis(imido) complex

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Published in 2018 at "Inorganica Chimica Acta"

DOI: 10.1016/j.ica.2017.08.050

Abstract: Abstract The coordination sphere of the reported (1,3-bis(3-butylimidazol-1-yl-2-idene)-2-phenylene)( tert -butylimido) CCC-NHC Ta (V) bis(imido) pincer complex 2 (Helgert et al., 2016, doi: 10.1021/acs.organomet.6b00216 ) has been observed to spontaneously rearrange to yield X-ray quality crystals… read more here.

Keywords: pincer; ccc; bis imido; ccc nhc ... See more keywords
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Synthesis, structure and biological activity of zinc(II) pincer complexes with 2,4-bis(3,5-dimethyl-1H-pyrazol-1-yl)-6-methoxy-1,3,5-triazine

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Published in 2020 at "Inorganica Chimica Acta"

DOI: 10.1016/j.ica.2020.119627

Abstract: Abstract The reaction of 2,4-bis(3,5-dimethyl-1H-pyrazol-1-yl)-6-methoxy-1,3,5-triazine (BPT) pincer ligand with Zn(NO3)2 and Zn(ClO4)2·6H2O/HCl yielded, [Zn(BPT)(NO3)2] (2), and [Zn(BPT)(H2O)Cl]ClO4 (3) complexes, respectively. However, zinc(II) chloride with BPT involved C N rupture and formed instead [Zn(DMP)2Cl2] (1) complex… read more here.

Keywords: pincer; methoxy triazine; dimethyl pyrazol; pyrazol methoxy ... See more keywords
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Unsymmetrical nickel (PCN) pincer complexes with a benzothiazole side-arm: Synthesis, characterization and electrochemical properties

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Published in 2020 at "Inorganica Chimica Acta"

DOI: 10.1016/j.ica.2020.120182

Abstract: Abstract The newly prepared unsymmetrical pincer ligand with a benzothiazole side-arm 2-(3-((di-tert-butylphosphino)methyl)phenoxy)benzo[d]thiazole [BzTz(H)PCN] has been reacted with anhydrous NiBr2 to get the corresponding NiII square planar bromo complex (BzTzPCN)NiBr (1) after HBr elimination and C−H… read more here.

Keywords: pincer; side arm; pcn; benzothiazole side ... See more keywords
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Synthesis and characterization of chiral enantiopure PC(sp)P pincer ligands and their complexes

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Published in 2021 at "Inorganica Chimica Acta"

DOI: 10.1016/j.ica.2021.120350

Abstract: Abstract This paper reports an efficient synthetic approach to preparing optically active PC(sp3)P pincer ligands and their complexes. The reported synthetic scheme relies on a simple and straightforward carbo-Diels–Alder reaction cycloaddition of a readily available… read more here.

Keywords: chiral enantiopure; synthesis characterization; pincer ligands; characterization chiral ... See more keywords
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POBOP pincer complexes of nickel(II): Synthesis and B H activation of the carborane ligand upon oxidation with iodine

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Published in 2017 at "Journal of Organometallic Chemistry"

DOI: 10.1016/j.jorganchem.2016.10.040

Abstract: Abstract The (POBOP)NiCl pincer complex (POBOP = 1,7-OP(i-Pr)2-m-carboranyl) was synthesized by the selective B H activation of the chelating carboranyl ligand and structurally and spectroscopically characterized. The reaction of (POBOP)NiCl and 1 equiv. of I2 at room… read more here.

Keywords: pobop; pincer; pobop nicl; pobop pincer ... See more keywords