Iron(III) Pincer Complexes as a Strategy for Anticancer Studies
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201601350
Abstract: [Fe(NCN)2]PF6 (1·PF6) [NCHN = 1,3-di(pyridin-2-yl)benzene] was readily obtained by a transmetalation reaction between [Fe3(CO)12] and Hg(NCN)Cl followed by a metathesis reaction with KPF6. X-ray diffraction, electron paramagnetic resonance spectroscopy, and cyclic voltammetry studies confirmed the… read more here.
Keywords: complexes strategy; iii pincer; anticancer studies; strategy anticancer ... See more keywords
Novel and facile procedure for the synthesis of Ni(II) and Pd(II) PSCOP pincer complexes. Evaluation of their catalytic activity on C-S, C-Se and C-C cross coupling reactions
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2019.119283
Abstract: Abstract A new and facile procedure for the synthesis of non-symmetric phosphinito-thiophosphinito PSCOP pincer complexes based on Ni(II) and Pd(II) was developed. The synthesis of the complexes was carried out in a single step, starting… read more here.
Keywords: pscop pincer; procedure synthesis; facile procedure; coupling reactions ... See more keywords
Synthesis, structure and biological activity of zinc(II) pincer complexes with 2,4-bis(3,5-dimethyl-1H-pyrazol-1-yl)-6-methoxy-1,3,5-triazine
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.119627
Abstract: Abstract The reaction of 2,4-bis(3,5-dimethyl-1H-pyrazol-1-yl)-6-methoxy-1,3,5-triazine (BPT) pincer ligand with Zn(NO3)2 and Zn(ClO4)2·6H2O/HCl yielded, [Zn(BPT)(NO3)2] (2), and [Zn(BPT)(H2O)Cl]ClO4 (3) complexes, respectively. However, zinc(II) chloride with BPT involved C N rupture and formed instead [Zn(DMP)2Cl2] (1) complex… read more here.
Keywords: pincer; methoxy triazine; dimethyl pyrazol; pyrazol methoxy ... See more keywords
POBOP pincer complexes of nickel(II): Synthesis and B H activation of the carborane ligand upon oxidation with iodine
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2016.10.040
Abstract: Abstract The (POBOP)NiCl pincer complex (POBOP = 1,7-OP(i-Pr)2-m-carboranyl) was synthesized by the selective B H activation of the chelating carboranyl ligand and structurally and spectroscopically characterized. The reaction of (POBOP)NiCl and 1 equiv. of I2 at room… read more here.
Keywords: pobop; pincer; pobop nicl; pobop pincer ... See more keywords
Cationic Ruthenium (II)-NHC Pincer Complexes with Hemilabile COD: Solid-state Structural Characterisation and Theoretical Study of an η2-(E,Z)-COD Ligand
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2021.122061
Abstract: Abstract Cationic Ru(II)-CNC pincer complexes (CNC = 2,6-bis(1-methylimidazol-2-ylidene)pyridine), [Ru(CNC)(η2:η2-COD)Cl]Cl (1a) (COD = 1,5-cyclooctadiene), [Ru(CNC)(η2:η2-COD)Cl]PF6 (1b), [Ru(CNC)(η2-COD)Cl2] (2), [Ru(CNC)(DMSO)2Cl]Cl (3a), and [Ru(CNC)(DMSO)2Cl]PF6 (3b) have been synthesised and characterised. Single-crystal x-ray diffraction studies of the complexes reveal that the COD ligand… read more here.
Keywords: cnc; cod; solid state; pincer complexes ... See more keywords
Bis-pyrazolyl-s-triazine Ni(II) pincer complexes as selective gram positive antibacterial agents; synthesis, structural and antimicrobial studies
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2019.05.103
Abstract: Abstract A new heteroleptic octahedral [NiL(H2O)3](NO3)2·1/2H2O complex with the tridentate pincer type ligand L; 2,4-bis(3,5-dimethyl-1H-pyrazol-1-yl)-6-methoxy-1,3,5-triazine, was synthesized and characterized using self assembly and single crystal X-ray diffraction, respectively. The Ni(II) ion is coordinated with one… read more here.
Keywords: antimicrobial studies; ligand; gram positive; triazine ... See more keywords
Experimental and DFT studies of metal pincer complexes: An insight on structures and bonding
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2021.130725
Abstract: Abstract Investigation on a catechol-thiosemicarbazone based tridentate NOS chelator and its octahedral pincer complexes with trivalent aluminum, chromium, iron and gallium is presented. The metal-ligands’ coordination amalgamation in all these complexes resulted in two planar… read more here.
Keywords: studies metal; dft studies; pincer; experimental dft ... See more keywords
The Influence of para Substituents in Bis(N-Heterocyclic Carbene) Palladium Pincer Complexes for Electrocatalytic CO2 Reduction.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.6b02213
Abstract: The effect of modifying the pyridyl para position of lutidine-linked bis(N-heterocyclic carbene) Pd pincer complexes is studied both experimentally (R = OMe, H, Br, and COOR) and computationally, showing a strong effect on the first… read more here.
Keywords: reduction; bis heterocyclic; heterocyclic carbene; para ... See more keywords
Chiral Bis(Phospholane) PCP Pincer Complexes: Synthesis, Structure, and Nickel-Catalyzed Asymmetric Phosphine Alkylation
Sign Up to like & getrecommendations! Published in 2018 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00284
Abstract: A known ligand precursor, prepared by an improved method from 1,3-bis(bromomethylbenzene), a base, and (R,R)-2,5-dimethylphospholane-borane, was deprotected with DABCO and used to prepare chiral m-xylene-based PCP pincer complexes. Reaction with Ni(DME)Br2 and NEt3 gave square… read more here.
Keywords: pincer; nickel; bis phospholane; pcp pincer ... See more keywords
Synthesis, Characterization, and Catalytic Studies of Unsymmetrical Chiral NCC Pincer Pd(II) and Ni(II) Complexes Bearing (Imidazolinyl)aryl NHC Ligands
Sign Up to like & getrecommendations! Published in 2018 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00300
Abstract: A series of palladium(II) and nickel(II) complexes based on unsymmetrical chiral (imidazolinyl)aryl NHC ligands are reported. The new ligand presursors 3a–g were prepared from commercially available 3-bromobenzoic acid, in which the carboxyl and bromo functionalities… read more here.
Keywords: pincer; aryl nhc; imidazolinyl aryl; unsymmetrical chiral ... See more keywords
Determining the Catalyst Properties That Lead to High Activity and Selectivity for Catalytic Hydrodeoxygenation with Ruthenium Pincer Complexes
Sign Up to like & getrecommendations! Published in 2020 at "Organometallics"
DOI: 10.1021/acs.organomet.9b00816
Abstract: Ten ruthenium pincer complexes were evaluated as catalysts for the hydrodeoxygenation (HDO) reaction on a lignin monomer surrogate, vanillyl alcohol. Four of these complexes are reported herein with the synthesis and full characterization data for… read more here.
Keywords: pincer; ruthenium pincer; hydrodeoxygenation; selectivity ... See more keywords