Dehydrogenation of amine–boranes catalyzed by a PCsp3P pincer iridium complex
Sign Up to like & getrecommendations! Published in 2020 at "Mendeleev Communications"
DOI: 10.1016/j.mencom.2020.05.004
Abstract: Dibenzobarrelene-based PC s p 3 P pincer iridium complex bearing dangling CH2OH groups, ( ( PC s p 3 P CH 2 OH ) IrH ( Cl ) , catalyzes the dehydrogenation of amine–boranes at… read more here.
Keywords: dehydrogenation amine; iridium complex; pincer iridium; amine boranes ... See more keywords
Synthesis and reactivity of PC(sp3)P-pincer iridium complexes bearing a diborylmethyl anion.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00513a
Abstract: Novel PCP-pincer iridium complexes bearing a diborylmethyl anion were synthesized. Strong σ-electron-donation to the metal and significant π-backdonation from the metal to boron atoms at the β-position were observed both experimentally and computationally. H/D exchange… read more here.
Keywords: bearing diborylmethyl; pincer iridium; iridium complexes; complexes bearing ... See more keywords