Articles with "pincer type" as a keyword



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Pincer‐type MRI morphology seen in over a third of asymptomatic healthy volunteers without femoroacetabular impingement

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Published in 2019 at "Journal of Magnetic Resonance Imaging"

DOI: 10.1002/jmri.26297

Abstract: In daily routine, pincer femoroacetabular impingement (FAI) findings are often seen without a clinical diagnosis of pincer FAI. read more here.

Keywords: pincer; femoroacetabular impingement; type mri; pincer type ... See more keywords
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Evaluation of the antitumor activity of a series of the pincer-type metallocomplexes produced from isonicotinohydrazide derivative.

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Published in 2021 at "Journal of inorganic biochemistry"

DOI: 10.1016/j.jinorgbio.2021.111525

Abstract: In this work we report on the antitumor properties of a series of pincer-type metallocomplexes [Hg2(HL-keto)Cl4]n (1), [Hg(HL-keto)I2] (2) and [Mn(HL-zwitterion)Cl2]∙MeOH (3∙MeOH), derived from N'-(1-(pyridin-2-yl)ethylidene)isonicotinohydrazide (HL) and corresponding metal salts. The Hg(II) and Mn(II) salts… read more here.

Keywords: type metallocomplexes; cell lines; pincer type; series pincer ... See more keywords
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Iron and ruthenium complexes having a pincer-type ligand with two protic amidepyrazole arms: Structures and catalytic application

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Published in 2017 at "Polyhedron"

DOI: 10.1016/j.poly.2017.08.044

Abstract: Abstract This paper describes the iron and ruthenium complexes ligated by 2,6-di(5-pivalamido-1H-pyrazol-3-yl)pyridine (amide-LH2) bearing electron-withdrawing NHCOBut groups on the two protic pyrazole arms. Treatment of FeCl2·4H2O with an equimolar amount of amide-LH2 followed by addition… read more here.

Keywords: ruthenium; iron ruthenium; amide lh2; pincer type ... See more keywords
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Exploring the Coordination Chemistry of N2 with Technetium PNP Pincer-Type Complexes.

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Published in 2021 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.1c00503

Abstract: Dinitrogen (N2) complexes of technetium (99Tc) are rare, and only two examples have been reported. To complement this important class of complexes also for 99Tc, two different pincer-type complexes of 99Tc were studied to assess… read more here.

Keywords: pincer; dinitrogen; type complexes; pincer type ... See more keywords
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Isolable Tin(II) Hydrides Featuring Sterically Undemanding Pincer-Type Ligands and Their Dehydrogenative Sn-Sn Bond Forming Reactions to Distannynes Promoted by Lewis Acidic Tri-sec-butylborane.

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Published in 2022 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.1c04019

Abstract: Unlike isolable tin(II) hydrides supported by bulky ligands reported in the literature, this research describes the synthesis and characterization of thermally stable tin(II) hydrides LPhSnH (1-H) and MeLSnH (2-H) stabilized by sterically undemanding N,N,N-coordinating pincer-type… read more here.

Keywords: sterically undemanding; pincer type; isolable tin; tin ... See more keywords
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Non-Pincer-Type Arene Ru(II) Catalysts for the Direct Synthesis of Azines from Alcohols and Hydrazine under Aerobic Conditions

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Published in 2020 at "Organometallics"

DOI: 10.1021/acs.organomet.0c00367

Abstract: We report a tandem approach to synthesize symmetrical azines from alcohols and hydrazine hydrate catalyzed by synthesized arene Ru(II) complexes of aroylthiourea ligand. Notably, the catalytic effi... read more here.

Keywords: azines alcohols; pincer type; non pincer; type arene ... See more keywords
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Counteranion-Controlled Ag2O-Mediated Benzimidazolium Ring Opening and Its Application in the Synthesis of Palladium Pincer-Type Complexes

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Published in 2017 at "Organometallics"

DOI: 10.1021/acs.organomet.7b00651

Abstract: We report a new approach to synthesize palladium complexes through Ag2O-promoted hydrolytic ring opening followed by palladium coordination. The novelty of Ag2O-promoted hydrolysis in comparison with the commonly used base-mediated hydrolysis lies in the anion-controlled… read more here.

Keywords: ring opening; palladium complexes; pincer type; palladium ... See more keywords
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Rhodium-Catalyzed Chemoselective Hydrosilylation of Nitriles to an Imine Oxidation Level Enabled by a Pincer-type Group 13 Metallylene Ligand

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Published in 2020 at "ACS Catalysis"

DOI: 10.1021/acscatal.0c02779

Abstract: Syntheses and catalytic application of rhodium complexes having a pincer-type group 13 metallylene ligand are reported. The PGaIP–Rh complex exhibited high chemoselectivity for hydrosilylation of n... read more here.

Keywords: type group; metallylene ligand; rhodium; group metallylene ... See more keywords
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Synthesis and some coordination chemistry of the PSnP pincer-type stannylene Sn(NCH2PtBu2)2C6H4, attempts to prepare the PSiP analogue, and the effect of the E atom on the molecular structures of E(NCH2PtBu2)2C6H4 (E = C, Si, Ge, Sn).

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Published in 2018 at "Dalton transactions"

DOI: 10.1039/c7dt04561a

Abstract: The non-donor-stabilized PSnP pincer-type stannylene Sn(NCH2PtBu2)2C6H4 (1) has been prepared by treating SnCl2 with Li2(NCH2PtBu2)2C6H4. All attempts to synthesize the analogous PSiP silylene by reduction of the (previously unknown) silanes SiCl2(NCH2PtBu2)2C6H4 (2), SiHCl(NCH2PtBu2)2C6H4 (3) and… read more here.

Keywords: pincer type; chemistry; psnp pincer; nch2ptbu2 2c6h4 ... See more keywords
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Metallo-supramolecular assembly of protic pincer-type complexes: encapsulation of dinitrogen and carbon disulfide into a multiproton-responsive diruthenium cage.

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Published in 2019 at "Chemical communications"

DOI: 10.1039/c8cc08384c

Abstract: Partial dehydrobromination of a diprotic pincer-type ruthenium complex in the presence of a rigid 1,3-bis(diphenylphosphino)benzene linker provided a dinuclear cage containing a guest template KBr surrounded by hydrogen bonds and electrostatic interactions. Dinitrogen and carbon… read more here.

Keywords: pincer; pincer type; carbon disulfide; dinitrogen carbon ... See more keywords
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Modulation of coordination in pincer-type isonicotinohydrazone Schiff base ligands by proton transfer

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Published in 2019 at "CrystEngComm"

DOI: 10.1039/c8ce01580e

Abstract: We report the synthesis and X-ray characterization and theoretical study of two Hg(ii) complexes with pincer-type isonicotinohydrazone Schiff base ligands to analyze chelate-ring π-stacked assemblies. read more here.

Keywords: pincer type; type isonicotinohydrazone; base ligands; isonicotinohydrazone schiff ... See more keywords