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Published in 2017 at "Journal of Chemical Sciences"
DOI: 10.1007/s12039-017-1350-y
Abstract: Five heteroleptic, cyclometalated (C$$^{\wedge }$$∧N) Iridium(III) complexes of acetylacetone (acac) and 1-phenyl-isoquinoline (piq) derivatives, Ir(acac)(piq)$$_{2}$$2, Ir(acac)(2,4-difluoro-piq)$$_{2}$$2, Ir(acac)(4-trifluoromethyl-piq)$$_{2}$$2, Ir(acac)(4-N,N-dimethyl-piq)$$_{2}$$2, Ir(acac)(4-acetyl-piq)$$_{2}$$2, were synthesized and characterized. The ($$\text {C}^{{\wedge }}\text {N})_{2}$$C∧N)2Ir(acac) complexes in toluene showed phosphorescence ($$\uplambda _{\max…
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Keywords:
iii;
electroluminescence;
photophysical electrochemical;
piq acac ... See more keywords