Articles with "pivalate" as a keyword



Evaluation of standard enthalpy of formation of copper(I) pivalate

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Published in 2017 at "Journal of Thermal Analysis and Calorimetry"

DOI: 10.1007/s10973-017-6583-y

Abstract: The evaluation technique of the standard enthalpy of formation was developed for pivalate complexes by means of differential scanning calorimetry method. The heating the binary system [(CH3)3CCOOAg + Cu] allowed to determine the standard enthalpy of the… read more here.

Keywords: enthalpy formation; pivalate; standard enthalpy;

Tetranuclear {CoII2CoIII2}, Octanuclear {CoII4CoIII4}, and Hexanuclear {CoIII3DyIII3} Pivalate Clusters: Synthesis, Magnetic Characterization, and Theoretical Modeling.

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Published in 2017 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.6b02827

Abstract: New tetranuclear and octanuclear mixed-valent cobalt(II/III) pivalate clusters, namely, [NaCo4(O2CCMe3)6(HO2CCMe3)2(teaH)2(N3)]·2H2O (in two polymorphic modifications, 1 and 1a) and [Co8(O2CCMe3)10(teaH)4(N3)](Me3CCO2)·MeCN·H2O (2) have been synthesized by ultrasonic treatment of a dinuclear cobalt(II) pivalate precursor with sodium azide… read more here.

Keywords: h2o; pivalate; o2ccme3 teah; cluster ... See more keywords

Pivalate complexes of copper(ii) with aliphatic amines as potential precursors for depositing nanomaterials from the gas phase

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Published in 2024 at "New Journal of Chemistry"

DOI: 10.1039/d3nj04959k

Abstract: New copper(ii) complexes [Cu2(RNH2)2(μ-O2CtBu)4]n can be promising for the vapour deposition methods (CVD and FEBID). The pivalate-amine ligand system allowed multinuclear single crystals to grow through the partial release of the secondary ligand. read more here.

Keywords: amines potential; complexes copper; copper aliphatic; pivalate complexes ... See more keywords

Genes and enzymes involved in the biodegradation of the quaternary carbon compound pivalate in the denitrifying Thauera humireducens strain PIV-1.

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Published in 2022 at "Environmental microbiology"

DOI: 10.1111/1462-2920.16021

Abstract: Quaternary carbon containing compounds exist in natural and fossil oil derived products and are used in chemical and pharmaceutical applications up to industrial scale. Due to the inaccessibility of the quaternary carbon atom for a… read more here.

Keywords: thauera humireducens; carbon; humireducens strain; quaternary carbon ... See more keywords

Synthesis and thermodynamics of lead(II), manganese(II), and cobalt(II) pivalate complexes

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Published in 2017 at "Russian Journal of Inorganic Chemistry"

DOI: 10.1134/s0036023617100060

Abstract: Manganese and cobalt oxopivalates and lead pivalate have been synthesized, mass spectral and thermogravimetric analysis have been performed. Sublimation enthalpies of cobalt and manganese oxopivalates have been determined for the first time, while the sublimation… read more here.

Keywords: thermodynamics lead; pivalate; thermodynamics; synthesis thermodynamics ... See more keywords