Origins of chemoselectivity of Rh(III)-Catalyzed C–H activation of N-(pivaloyloxy)benzamide: Insights from density functional theory calculations
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DOI: 10.1016/j.jorganchem.2018.11.011
Abstract: Abstract An unprecedented Rh(III)-catalyzed C–H activation of N-(pivaloyloxy)benzamide was recently reported by Feng et al. In this transformation, the substituent on the alkyne controls the chemoselectivity (annulation or hydroarylation). Given the importance of this novel strategy,… read more here.
Keywords: iii catalyzed; chemoselectivity; catalyzed activation; activation pivaloyloxy ... See more keywords