Plasmon-generated hot holes for chemical reactions
Sign Up to like & getrecommendations! Published in 2020 at "Nano Research"
DOI: 10.1007/s12274-020-3031-2
Abstract: Plasmonic nanostructures have been widely used for photochemical conversions due to their unique and easy-tuning optical properties in visible and near-infrared range. Compared with the plasmon-generated hot electrons, the hot holes usually have a shorter… read more here.
Keywords: holes chemical; plasmon generated; chemical reactions; generated hot ... See more keywords
Manipulating Plasmon-Generated Hot Carriers for Photocatalysis.
Sign Up to like & getrecommendations! Published in 2025 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.5c00313
Abstract: ConspectusLocalized surface plasmon resonance (LSPR), a distinctive optoelectronic property of plasmonic nanocrystals, arises from the collective oscillation of conduction electrons in resonance with incident light. The excitation of LSPR confines incident light near the surface… read more here.
Keywords: hot carriers; chemical reactions; generated hot; plasmonic nanocrystals ... See more keywords
Elucidating the Origin of Plasmon-Generated Hot Holes in Water Oxidation.
Sign Up to like & getrecommendations! Published in 2023 at "ACS nano"
DOI: 10.1021/acsnano.3c00758
Abstract: Plasmon-generated hot electrons in metal/oxide heterostructures have been used extensively for driving photochemistry. However, little is known about the origin of plasmon-generated hot holes in promoting photochemical reactions. Herein, we discover that, during the nonradiative… read more here.
Keywords: oxidation; water; plasmon generated; hot holes ... See more keywords
Plasmon-Generated Solvated Electrons for Chemical Transformations.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c07768
Abstract: Methods for generating solvated electrons─free electrons in solution─have focused primarily on alkali metal ionization or high-energy electrons or photons. Here we report the generation of solvated electrons by exciting the plasmon resonance of Al nanocrystals… read more here.
Keywords: reaction; chemical transformations; plasmon generated; solvated electrons ... See more keywords