Platinum catalyzed alkene hydrosilylation: solvent-free process development from batch to a membrane-integrated continuous process.
Sign Up to like & getrecommendations! Published in 2021 at "ChemSusChem"
DOI: 10.1002/cssc.202101153
Abstract: The integration of a membrane separation protocol with the platinum-catalyzed hydrosilylation of olefins was investigated. The catalytic reaction was first optimized in batch where [Pt(IPr*)(DMS)Cl 2 ] (IPr* = 1,3-bis[2,6-bis(diphenylmethyl)-4-methylphenyl]imidazol- 2-ylidene , DMS = dimethyl… read more here.
Keywords: platinum catalyzed; process; solvent free; membrane ... See more keywords
Study of the products of platinum-catalyzed hydrogenation of chlorinated nitro and amino aromatic compounds at high degree of dehalogenation
Sign Up to like & getrecommendations! Published in 2018 at "Russian Chemical Bulletin"
DOI: 10.1007/s11172-018-2233-1
Abstract: The kinetics of formation and consumption of the dehalogenation products during hydrogenation of 3,4-dichloronitrobenzene under static and gradient-free flow conditions and hydrogenation of p-chloroaniline under static conditions were studied in the presence of platinum supported… read more here.
Keywords: dehalogenation; products platinum; platinum catalyzed; hydrogenation ... See more keywords
Platinum-catalyzed reactions of 2,3-bis(dimethylsilyl)furan with alkynes
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2017.10.016
Abstract: Abstract The synthesis and platinum-catalyzed reactions of 2,3-bis(dimethylsilyl)furan (1) have been reported. The reactions of 1 with diphenylacetylene and phenyl(trimethylsilyl)acetylene in the presence of a platinum catalyst gave the corresponding six-membered ring compounds produced from… read more here.
Keywords: platinum catalyzed; catalyzed reactions; reactions bis; dimethylsilyl furan ... See more keywords
Effect of Buchwald-type ligands on platinum catalyzed hydrosilylation of vinyl terminated polydimethylsiloxane
Sign Up to like & getrecommendations! Published in 2019 at "Mendeleev Communications"
DOI: 10.1016/j.mencom.2019.07.035
Abstract: The effect of Buchwald-type ligands on the platinum catalyzed hydrosilylation of vinyl-terminated polydimethylsiloxane has been studied by differential scanning calorimetry of platinum catalyst-containing silicone compositions. Dialkyl(biphenyl-2-yl)phosphines bearing bulky substituents at phosphorus atom are efficient inhibitors… read more here.
Keywords: buchwald type; hydrosilylation; type ligands; ligands platinum ... See more keywords
Platinum-Catalyzed C-H Functionalization.
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DOI: 10.1021/acs.chemrev.6b00583
Abstract: Recent developments in C-H bond activation and functionalization by Pt complexes are surveyed. Topics include the following: fundamental mechanistic investigations of C-H activation; stoichiometric intra- and intermolecular C-H activation; reactions of dioxygen with Pt(II) complexes… read more here.
Keywords: platinum catalyzed; functionalization; catalyzed functionalization; activation ... See more keywords
Platinum-catalyzed selective N-allylation of 2,3-disubstituted indoles with allylic acetates in water
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DOI: 10.1039/c8nj05051a
Abstract: Herein, we have demonstrated that the platinum-catalyzed selective N-allylation of 2,3-disubstituted indoles proceeds in water. read more here.
Keywords: allylation disubstituted; selective allylation; disubstituted indoles; platinum catalyzed ... See more keywords