Organic-inorganic hybrids assembled from plenary Keggin-type germanotungstate units and 3d-4f heterometal clusters.
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DOI: 10.1039/c9dt00312f
Abstract: Two kinds of organic-inorganic 3d-4f heterometal hybrids based on plenary α-Keggin-type germanotungstates [Cu2(H2O)3(PA)3] [Ln0.5Na0.5Cu2(H2O)12(PA)3][α-GeW12O40]·5H2O [Ln = La3+ (1), Ce3+ (2)] and [Cu2(H2O)2(PA)3][Cu(PA)2][Ln(H2O)7][α-GeW12O40]·7H2O [Ln = Tb3+ (3), Dy3+ (4), HPA = 2-picolinic acid] were prepared via… read more here.
Keywords: organic inorganic; h2o; keggin type; cu2 h2o ... See more keywords