Neutral and Cationic Complexes of Silicon(IV) Halides with Phosphine Ligands
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.2c02949
Abstract: The reaction of SiI4 and PMe3 in n-hexane produced the yellow salt, [SiI3(PMe3)2]I, confirmed from its X-ray structure, containing a trigonal bipyramidal cation with trans-phosphines. This contrasts with the six-coordination found in (the known) trans-[SiX4(PMe3)2]… read more here.
Keywords: pme3 barf; pme3; six4 pme3; charge ... See more keywords