Monomeric nickel hydroxide stabilized by a sterically demanding phosphorus-nitrogen PN3P-pincer ligand: synthesis, reactivity and catalysis.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt03403f
Abstract: A terminal nickel hydroxide complex (PN3P)Ni(OH) (3) bearing the 2nd generation phosphorus-nitrogen PN3P-pincer ligand has been synthesized and structurally characterized. As a nucleophile, 3 reacts with CO to afford the hydroxycarbonyl complex 4, (PN3P)Ni(COOH). 3… read more here.
Keywords: pincer ligand; pn3p; nickel hydroxide; nitrogen pn3p ... See more keywords
Catalytic Ammonia Synthesis Mediated by Molybdenum Complexes with PN3P Pincer Ligands: Influence of P/N Substituents and Molecular Mechanism
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27227843
Abstract: Three molybdenum trihalogenido complexes supported by different PN3P pincer ligands were synthesized and investigated regarding their activity towards catalytic N2-to-NH3 conversion. The highest yields were obtained with the H-PN3PtBu ligand. The corresponding Mo(V)-nitrido complex also… read more here.
Keywords: catalytic ammonia; molybdenum; mechanism; pincer ligands ... See more keywords