Systematic Study of Pnictogen-Fused Heterofluorenes.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00158
Abstract: Heteroatom-fused π-conjugated molecules have attracted considerable attention, and various elements for such fusion have been investigated. Herein, we focused on pnictogen-fused heterofluorenes. The structures, reactivity with O2 and I2, coordination ability to AuCl, and photophysical… read more here.
Keywords: pnictogen fused; chemistry; fused heterofluorenes; pnictogen ... See more keywords
Anion Transport with Pnictogen Bonds in Direct Comparison with Chalcogen and Halogen Bonds.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b12554
Abstract: In this Communication, we introduce transmembrane anion transport with pnictogen-bonding compounds and compare their characteristics with chalcogen- and halogen-bonding analogues. Tellurium-centered chalcogen bonds are at least as active as antimony-centered pnictogen bonds, whereas iodine-centered halogen… read more here.
Keywords: anion transport; anion; pnictogen; halogen ... See more keywords
General Synthetic Route to High Quality Colloidal III-V Semiconductor Quantum Dots Based on Pnictogen Chlorides.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b06652
Abstract: The synthesis of colloidal III-V quantum dots (QDs), particularly of the arsenides and antimonides, has been limited by the lack of stable and available group V precursors. In this work, we exploit accessible InCl3- and… read more here.
Keywords: iii; general synthetic; pnictogen; colloidal iii ... See more keywords
The pnictogen bond: a quantitative molecular orbital picture†
Sign Up to like & getrecommendations! Published in 2021 at "Physical Chemistry Chemical Physics"
DOI: 10.1039/d1cp01571k
Abstract: We have analyzed the structure and stability of archetypal pnictogen-bonded model complexes D3Pn⋯A− (Pn = N, P, As, Sb; D, A = F, Cl, Br) using state-of-the-art relativistic density functional calculations at the ZORA-M06/QZ4P level.… read more here.
Keywords: pnictogen bond; bond quantitative; pnictogen; molecular orbital ... See more keywords