The pnictogen bond: a quantitative molecular orbital picture†
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DOI: 10.1039/d1cp01571k
Abstract: We have analyzed the structure and stability of archetypal pnictogen-bonded model complexes D3Pn⋯A− (Pn = N, P, As, Sb; D, A = F, Cl, Br) using state-of-the-art relativistic density functional calculations at the ZORA-M06/QZ4P level.… read more here.
Keywords: pnictogen bond; bond quantitative; pnictogen; molecular orbital ... See more keywords
The Stibium Bond or the Antimony-Centered Pnictogen Bond: The Covalently Bound Antimony Atom in Molecular Entities in Crystal Lattices as a Pnictogen Bond Donor
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DOI: 10.3390/ijms23094674
Abstract: A stibium bond, i.e., a non-covalent interaction formed by covalently or coordinately bound antimony, occurs in chemical systems when there is evidence of a net attractive interaction between the electrophilic region associated with an antimony… read more here.
Keywords: bond; stibium bond; pnictogen bond; molecular entities ... See more keywords
The Pnictogen Bond, Together with Other Non-Covalent Interactions, in the Rational Design of One-, Two- and Three-Dimensional Organic-Inorganic Hybrid Metal Halide Perovskite Semiconducting Materials, and Beyond
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DOI: 10.3390/ijms23158816
Abstract: The pnictogen bond, a somewhat overlooked supramolecular chemical synthon known since the middle of the last century, is one of the promising types of non-covalent interactions yet to be fully understood by recognizing and exploiting… read more here.
Keywords: pnictogen bond; non covalent; metal halide; covalent interactions ... See more keywords
The Phosphorus Bond, or the Phosphorus-Centered Pnictogen Bond: The Covalently Bound Phosphorus Atom in Molecular Entities and Crystals as a Pnictogen Bond Donor
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DOI: 10.3390/molecules27051487
Abstract: The phosphorus bond in chemical systems, which is an inter- or intramolecular noncovalent interaction, occurs when there is evidence of a net attractive interaction between an electrophilic region associated with a covalently or coordinately bonded… read more here.
Keywords: phosphorus centered; pnictogen bond; phosphorus bond; phosphorus ... See more keywords
The Pnictogen Bond: The Covalently Bound Arsenic Atom in Molecular Entities in Crystals as a Pnictogen Bond Donor
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DOI: 10.3390/molecules27113421
Abstract: In chemical systems, the arsenic-centered pnictogen bond, or simply the arsenic bond, occurs when there is evidence of a net attractive interaction between the electrophilic region associated with a covalently or coordinately bound arsenic atom… read more here.
Keywords: interaction; pnictogen bond; atom molecular; arsenic atom ... See more keywords