Synthesis and characterization of unsaturated Manganese(I) and Rhenium(I) dicarbonyl complexes supported by an anionic PNP pincer
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2019.06.020
Abstract: Abstract Syntheses of Re and Mn carbonyl complexes of the diarylamido/bis(phosphine) PNP pincer ligand are reported. The saturated (PNP)Re(CO)3 and (PNP)Mn(CO)3 react cleanly with HBr in acetic acid to undergo decarbonylation with concomitant addition of… read more here.
Keywords: synthesis characterization; unsaturated manganese; characterization unsaturated; pnp ... See more keywords
Supramolecular structures of V(III) complexes supported by PNP pincer ligands
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2017.07.066
Abstract: Abstract The syntheses of vanadium complexes with tridentate PNP pincer ligands based on 2,6-diaminopyridine of the type [(PNP)VCl 3 ] are reported. All compounds reveal distorted octahedral metal coordination geometry with three meridionally placed donor… read more here.
Keywords: pnp pincer; structures iii; supramolecular structures; pincer ligands ... See more keywords
Asymmetric Induction with a Chiral Amine Catalyzed by a Ru-PNP Pincer Complex: Insight from Theoretical Investigation.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c00823
Abstract: In this paper, the mechanism of asymmetric amination of a racemic alcohol with Ellman's sulfinamide and the origin of diastereoselectivity catalyzed by a Ru-PNP pincer complex were studied using density functional theory (DFT). The mechanism… read more here.
Keywords: pincer complex; catalyzed pnp; induction chiral; pnp pincer ... See more keywords
Cu(i) complex bearing a PNP-pincer-type phosphaalkene ligand with a bulky fused-ring Eind group: properties and applications to FLP-type bond activation and catalytic CO2 reduction.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/d0dt00276c
Abstract: Herein, we report the synthesis of [Cu(Eind2-BPEP)][PF6] (2) (Eind2-BPEP = 2,6-bis(2-Eind-2-phosphaethenyl)pyridine, Eind = 1,1,3,3,5,5,7,7-octaethyl-1,2,3,5,6,7-hexahydro-s-indacen-4-yl), a three-coordinated Cu(i) complex bearing a PNP-pincer-type phosphaalkene ligand with bulky fused-ring Eind groups. The Gutmann-Beckett test revealed that complex 2… read more here.
Keywords: complex bearing; bulky; pnp pincer; pincer type ... See more keywords
Reactions of Rh(PNP) pincer complexes with terminal alkynes: homocoupling through a ring or not at all.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/d0dt03550e
Abstract: Through use of a bespoke macrocyclic variant, we demonstrate a novel approach for tuning the reactivity of rhodium PNP pincer complexes that enables formation of conjugated enynes from terminal alkynes, rather than vinylidene derivates. This… read more here.
Keywords: pnp pincer; terminal alkynes; reactions pnp; complexes terminal ... See more keywords
Theoretical mechanistic insights into dinitrogen cleavage by a dititanium hydride complex bearing PNP-pincer ligands.
Sign Up to like & getrecommendations! Published in 2021 at "Dalton transactions"
DOI: 10.1039/d1dt03852d
Abstract: The mechanism of dinitrogen cleavage by a PNP-coordinated dititanium polyhydride complex has been computationally investigated. A "multi-state reactivity" scenario has been disclosed for the whole process of N2 coordination and activation. Remarkably, the H2 elimination… read more here.
Keywords: cleavage; pnp pincer; dinitrogen cleavage;