Benzylene-linked [PNP] scaffolds and their cyclometalated zirconium and hafnium complexes.
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DOI: 10.1039/c7dt00413c
Abstract: The benzylene-linked [PNP] scaffolds HN(CH2-o-C6H4PPh2)2 ([A]H) and HN(C6H4-o-CH2PPh2)2 ([B]H) have been used for the synthesis of zirconium and hafnium complexes. For both ligands, the dimethylamides [A]M(NMe2)3 ([A]1-M) and [B]M(NMe2)3 ([B]1-M) were prepared and converted to… read more here.
Keywords: benzylene linked; pnp scaffolds; zirconium; linked pnp ... See more keywords