Trimethylsilyl imide complexes of tantalum: Can the silyl group be eliminated?
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DOI: 10.1016/j.poly.2016.09.042
Abstract: Abstract We report the synthesis and structure of a series of tantalum(V) complexes having the trimethylsilylimide moiety and using as ancillary support the pincer ligand PNP (PNP− = N[2-PiPr2-4-methylphenyl]2). Via transmetallation of Li(PNP) with Cl3(py)2Ta N{SiMe3} (py = pyridine),… read more here.
Keywords: pnp; imide complexes; trimethylsilyl imide; pnp sime3 ... See more keywords