Linear-to-λ-Shape P-O-P Bond Transmutation in Polyphosphates with Infinite (PO3)∞ Chain.
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DOI: 10.1021/acs.inorgchem.7b01540
Abstract: A new metal polyphosphate, α-CsBa2(PO3)5, exhibiting the first example of a linear P-O-P bond angle in a one-dimensional (PO3)∞ chain has been reported. Interestingly, α → β phase transition occurs in CsBa2(PO3)5 along with the… read more here.
Keywords: po3 chain; bond; linear shape; po3 ... See more keywords