Continuous-/Micro-Flow Reactions Using Highly Electrophilic PCl3 and POCl3.
Sign Up to like & getrecommendations! Published in 2023 at "ChemPlusChem"
DOI: 10.1002/cplu.202300176
Abstract: PCl3 and POCl3 are the most important sources of phosphorus-containing compounds. They are also used for large-scale industrial productions. However, chemical reactions using the highly reactive PCl3 and POCl3 tend to result in overreactions. In… read more here.
Keywords: pcl3 pocl3; micro flow; pocl3; using highly ... See more keywords
Pentavalent P…π phosphorus bonding with associated Cl…π halogen bonding in influencing the geometry of POCl3-Phenylacetylene heterodimers: Evidence from matrix isolation infrared spectroscopy and ab initio computations
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2020.129288
Abstract: Abstract Of the two diverse oxidation states, phosphorus exists in its pentavalent state in a majority of real-life systems. In the present study, the role of Cl…π halogen bonding with co-operative pentavalent P…π phosphorus bonding in… read more here.
Keywords: phosphorus bonding; spectroscopy; halogen bonding; geometry ... See more keywords
Improved emitter performance of RIE black silicon through the application of in-situ oxidation during POCl3 diffusion
Sign Up to like & getrecommendations! Published in 2020 at "Solar Energy Materials and Solar Cells"
DOI: 10.1016/j.solmat.2020.110480
Abstract: Abstract Nano-texture has the potential to reduce the optical losses of crystalline silicon solar cells. RIE fabricated black silicon enables near zero reflectance across a broad range of wavelengths and the angular dependence has been… read more here.
Keywords: pocl3; emitter; performance; situ oxidation ... See more keywords