A POCO type pincer complex of iridium: Synthesis, characterization, and catalysis
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DOI: 10.1016/j.poly.2018.12.001
Abstract: Abstract A convenient synthesis of a new POCO-type pincer ligand, “tBuPOCOH”, (3-(di-tert-butylphosphinito)acetophenone is reported. Metallation using [Ir(COD)Cl]2 provides the dimeric species (μ-Cl-[tBuPOCOIrHCl]2) (1a) as a major product, along with isomer 1b. Though not fully characterized,… read more here.
Keywords: iridium; synthesis; pincer; poco type ... See more keywords