How does the carbon hybridization impact the rate of metal-carbon bond cleavage by an alkyne? A case study with POCOP-pincer ligated palladium hydrocarbyl complexes
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DOI: 10.1016/j.jorganchem.2017.04.024
Abstract: Abstract POCOP-pincer ligated palladium hydrocarbyl complexes [2,6-(R2PO)2C6H3]PdR′ have been prepared from the reaction between [2,6-(R2PO)2C6H3]PdCl and R'Li. X-ray crystallographic studies of these complexes show that the Pd–R′ bond becomes shorter when the metal-bound carbon has… read more here.
Keywords: carbon; bond; palladium hydrocarbyl; palladium ... See more keywords
Synthesis, characterization and catalytic evaluation of non-symmetric Pd(II)-POCOP pincer compounds derived from 2′,4′-Dihydroxyacetophenone
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DOI: 10.1016/j.jorganchem.2017.11.030
Abstract: Abstract A series of non-symmetric Pd(II)-POCOP pincer complexes were synthesized in a facile manner from the commercially available starting material 2′,4′-dihydroxyacetophenone. The preparation of the complexes was carried out in a single step affording the… read more here.
Keywords: pincer; non symmetric; pocop pincer; symmetric pocop ... See more keywords