Impact of Solvent Polarity on the Ligand Configuration in Tetravalent Thorium N-Donor Complexes.
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DOI: 10.1021/acs.inorgchem.0c03213
Abstract: A combined NMR spectroscopic and theoretical study on the complexation of diamagnetic Th(IV) with 2,6-bis(5,6-dipropyl-1,2,4-triazin-3-yl)pyridine (nPr-BTP) was performed. Different ligand configurations were observed for [Th(nPr-BTP)3]4+ complexes depending on the solvent's ability to actively form hydrogen… read more here.
Keywords: solvent polarity; polarity ligand; btp; impact solvent ... See more keywords