Selective Semihydrogenation of Polarized Alkynes by a Gold Hydride Nanocluster.
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DOI: 10.1021/jacs.2c05046
Abstract: The hydridic hydrogen in nanogold catalysts has long been postulated as an important intermediate in hydrogenation reactions, but it has not been directly observed. Here, we report the synthesis of a new undecagold cluster with… read more here.
Keywords: polarized alkynes; alkynes gold; semihydrogenation polarized; cluster ... See more keywords