Synthesis, Characterization, and Properties of Poly(aryl)phosphinoboranes Formed via Iron‐Catalyzed Dehydropolymerization
Sign Up to like & getrecommendations! Published in 2017 at "Macromolecular Chemistry and Physics"
DOI: 10.1002/macp.201700120
Abstract: The dehydropolymerization of the primary phosphine–boranes, RPH2•BH3 (1a–f) (R = 3,4-(OCH2O)C6H3 (a), Ph (b), p-(CF3O)C6H4 (c), 3,5-(CF3)2C6H3 (d), 2,4,6-(CH3)3C6H2 (e), 2,4,6-tBu3C6H2 (f)) is explored using the precatalyst [CpFe(CO)2OTf] (I) (OTf = OS(O)2CF3), based on the… read more here.
Keywords: dehydropolymerization; properties poly; aryl phosphinoboranes; characterization properties ... See more keywords
Palladium-Catalyzed Polycondensation for the Synthesis of Poly(Aryl)Sulfides.
Sign Up to like & getrecommendations! Published in 2020 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202000067
Abstract: The palladium-catalyzed CS cross coupling reaction is investigated as a novel efficient tool for the synthesis of poly(phenyl)sulfide derivatives. The reaction proceeds through the polycondensation of dibromo arenes with a H2 S-surrogate to yield poly(aryl)sulfides.… read more here.
Keywords: synthesis poly; poly; palladium catalyzed; polycondensation ... See more keywords
Self-cleaning and Oil/Water Separation of 3D Network Super-hydrophobic Bead-like Fluorinated Silica Pellets/Poly(aryl ether ketone) Composite Membrane Fabricated via a Facile One-step Electrospinning
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Research in Chinese Universities"
DOI: 10.1007/s40242-020-0085-3
Abstract: Novel super-hydrophobic fluorinated silica pellets/poly(aryl ether ketone) composite membranes with controllable structure have been prepared through incorporating poly(aryl ether ketone)s with (3-trifluoromethyl)-phenyl side groups and fluorinated silica pellets(F-SiO 2 ) by a facile one-step electrospinning.… read more here.
Keywords: aryl ether; water; silica pellets; poly aryl ... See more keywords
Effect of Phthalazinone Moiety on Sulfonated Poly(aryl ether ketone) Membranes for Water Vapor Permeability
Sign Up to like & getrecommendations! Published in 2021 at "Chemical Engineering Science"
DOI: 10.1016/j.ces.2021.116775
Abstract: Abstract Membrane technology is widely used in many industries for water vapor removal, however, few membranes can maintain permeance and selectivity at higher temperature. Poly(aryl ether ketone) membranes including sulfonated poly(ether ether ketone) (SPEEK), sulfonated… read more here.
Keywords: water; sulfonated poly; poly aryl; water vapor ... See more keywords
Ionic crosslinking of imidazolium functionalized poly(aryl ether ketone) by sulfonated poly(ether ether ketone) for anion exchange membranes.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of colloid and interface science"
DOI: 10.1016/j.jcis.2017.03.033
Abstract: Two N3-substituted imidazoles 1,2-dimethylimidazole and 1-butyl-2-methylimidazole were chosen to functionalize poly(aryl ether ketone), respectively. The generated imidazolium cations could electrostatically react with sulfonate ions of the sulfonated poly(ether ether ketone) forming the ionic crosslinking structure… read more here.
Keywords: aryl ether; ether ketone; ketone; exchange ... See more keywords
Prepared poly(aryl piperidinium) anion exchange membranes for acid recovery to improve dialysis coefficients and selectivity
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Membrane Science"
DOI: 10.1016/j.memsci.2020.118805
Abstract: Abstract The diffusion dialysis (DD) process based on AEM is considered for the acid recovery from acid effluents. In this work, the novel self-organized nanostructured cross-linked AEMs based on poly (aryl piperidinium) are synthesized for… read more here.
Keywords: acid recovery; recovery; poly aryl; dialysis ... See more keywords
High-expanded foams based on novel long-chain branched poly(aryl ether ketone) via ScCO2 foaming method
Sign Up to like & getrecommendations! Published in 2019 at "Polymer"
DOI: 10.1016/j.polymer.2019.01.039
Abstract: Abstract In this work, a new strategy was proposed to improve the foamability of poly(aryl ether ketone) (PAEK) based on novel long-chain branched PAEK (LCB-PAEK). To improve the resin melt strength, the amorphous LCB-PAEK was… read more here.
Keywords: chain; based novel; aryl ether; poly aryl ... See more keywords
Preparation and characterization of side-chain poly(aryl ether ketone) anion exchange membranes by superacid-catalyzed reaction
Sign Up to like & getrecommendations! Published in 2021 at "Polymer"
DOI: 10.1016/j.polymer.2021.123639
Abstract: ABSTRACT The poly(aryl ether ketone) with spatial cardo structure is prepared from 4,4'-bis(phenoxy)benzophenone and 1-(4-bromobutyl)indoline-2,3-dione through a facile polyhydroxyalkylation reaction catalyzed by superacid. The number average molecular weight of the resultant polymer is achieved as… read more here.
Keywords: anion; anion exchange; aryl ether; poly aryl ... See more keywords
Poly(aryl ether ketone) membrane with controllable degree of sulfonation for organic solvent nanofiltration
Sign Up to like & getrecommendations! Published in 2021 at "Separation and Purification Technology"
DOI: 10.1016/j.seppur.2021.118956
Abstract: Abstract The separation of organic solvents can be improved in a sustainable way by implementing membranes produced via streamlined processing. However, conventional membranes are not typically used in organic solvents, and thus require further chemical… read more here.
Keywords: degree sulfonation; organic solvent; membrane; aryl ether ... See more keywords
Phosphinated Poly(aryl ether)s with Acetic/Phenyl Methacrylic/Vinylbenzyl Ether Moieties for High-Tg and Low-Dielectric Thermosets
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DOI: 10.1021/acsomega.8b00615
Abstract: To achieve insulating materials with a low-dielectric characteristic for high-frequency communication applications, three phosphinated poly(aryl ether)s: P1-act (with acetic moiety), P1-mma (with phenyl methacrylic moiety), and P1-vbe (with vinylbenzyl ether moiety) were modified from a… read more here.
Keywords: aryl ether; vinylbenzyl ether; phosphinated poly; low dielectric ... See more keywords
Photo-directing chemoepitaxy: the versatility of poly(aryl methacrylate) films in tuning block copolymer wetting
Sign Up to like & getrecommendations! Published in 2021 at "Polymer Chemistry"
DOI: 10.1039/d1py00501d
Abstract: Photo-directed orientation control of block copolymer (BCP) domains is a powerful method for generating distinct regions of perpendicular and parallel-aligned lamella in a single film layer. In this study we demonstrate the versatility of aromatic… read more here.
Keywords: methacrylate; block copolymer; methacrylate films; photo ... See more keywords