Structure and Properties of Poly-α-olefins Containing Quaternary Carbon Centers
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DOI: 10.1021/acsomega.9b04361
Abstract: In this paper, poly-α-olefins (PAO) containing quaternary carbon centers were prepared by two-step oligomerization using a metallocene catalyst followed by a Ziegler–Natta catalyst. First, the 1-decene dimer was oligomerized with [t-BuN(Me)2C(η5-C5H4)]ZrCl2, and the effects of… read more here.
Keywords: product; containing quaternary; carbon centers; quaternary carbon ... See more keywords
Rationalizing chain microstructure in the polyα-olefins synthesized by cationic AlCl3/H2O catalytic system
Sign Up to like & getrecommendations! Published in 2019 at "International Journal of Polymer Analysis and Characterization"
DOI: 10.1080/1023666x.2019.1627027
Abstract: Abstract In this study, three middle range α-olefin monomers including 1-hexene, 1-octene, and 1-decene were oligomerized using conventional AlCl3/H2O catalytic system. Molecular weight and microstructure of the oligomers were analyzed by GPC and 1HNMR, respectively.… read more here.
Keywords: alcl3 h2o; poly olefins; catalytic system; h2o catalytic ... See more keywords