Synthesis of Poly(phenyltriazolylcarboxylate)s with Aggregation-Induced Emission Characteristics by Metal-Free 1,3-Dipolar Polycycloaddition of Phenylpropiolate and Azides.
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DOI: 10.1002/marc.201600745
Abstract: Two soluble poly(phenyltriazolylcarboxylate)s (PPTCs) with high molecular weights (M w up to 26 800) are synthesized by the metal-free 1,3-dipolar polycycloadditions of 4,4'-isopropylidenediphenyl diphenylpropiolate (1) and tetraphenylethene-containing diazides (2) in dimethylformamide at 150 °C for… read more here.
Keywords: aggregation; aggregation induced; poly phenyltriazolylcarboxylate; metal free ... See more keywords
Construction of Functional Hyperbranched Poly(phenyltriazolylcarboxylate)s by Metal-Free Phenylpropiolate-Azide Polycycloaddition.
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DOI: 10.1002/marc.201800604
Abstract: The 1,3-dipolar cycloaddition of activated internal alkynes with azides has been developed into an efficient polymerization reaction for constructing functional linear 1,4,5-trisubstitued polytriazoles. However, it is rarely employed for the synthesis of hyperbranched polymers. In… read more here.
Keywords: functional hyperbranched; hyperbranched poly; poly phenyltriazolylcarboxylate; construction functional ... See more keywords