A new octa-Mn-substituted poly(polyoxotungstate).
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DOI: 10.1039/c9dt02805f
Abstract: A novel octa-Mn-substituted silicotungstate (ST) [H2N(CH3)2]8H19Na4{[K(H2O)4WO4][SiMnII2W10O38]3}[SiMnIII2W10O38]·27H2O (1) has been made by the hydrothermal reaction of the trivacant [A-α-SiW9O34]10- ({SiW9}) building block with Mn2+ and Mn7+ cations in the presence of dimethylamine hydrochloride and systematically characterized… read more here.
Keywords: octa substituted; new octa; substituted poly; spectroscopy ... See more keywords