Synthesis and post-polymerization modification of poly(propargyl 2-ylidene-acetate)
Sign Up to like & getrecommendations! Published in 2021 at "European Polymer Journal"
DOI: 10.1016/j.eurpolymj.2021.110564
Abstract: Abstract Rhodium(I)-catalyzed C1 polymerization of propargyl 2-diazoacetate was conducted for the first time resulting in a novel functional polymethylene derivative, poly(propargyl 2-ylidene-acetate), which is suitable for a subsequent post-polymerization modification under mild reaction conditions via… read more here.
Keywords: post; propargyl ylidene; polymerization; modification ... See more keywords
Synthesis of Functional Poly(propargyl imine)s by Multicomponent Polymerizations of Bromoarenes, Isonitriles, and Alkynes
Sign Up to like & getrecommendations! Published in 2017 at "ACS Macro Letters"
DOI: 10.1021/acsmacrolett.7b00872
Abstract: Here we reported a versatile and multicomponent polymerization (MCP) approach that enabled the synthesis of functional poly(propargyl imine)s with well-defined structures and high molecular weight (Mw up to 38 200) in excellent yields (up to 93%)… read more here.
Keywords: synthesis functional; functional poly; propargyl imine; poly propargyl ... See more keywords