Hydrolyzable Poly(β-Thioether Ester Ketal) Thermosets via Acyclic Ketal Monomers.
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DOI: 10.1002/marc.202200028
Abstract: Hydrolytically degradable poly(β-thioether ester ketal) thermosets are synthesized via radical-mediated thiol-ene photopolymerization using three novel dialkene acyclic ketal monomers and a mercaptopropionate based tetrafunctional thiol. For all thermoset compositions investigated, degradation behavior is highly tunable… read more here.
Keywords: acyclic ketal; ester ketal; thioether ester; thioether ... See more keywords
Synthesis, characterization and potential applications of 5-hydroxymethylfurfural derivative based poly(β-thioether esters) synthesized via thiol-Michael addition polymerization
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DOI: 10.1039/c7py02052j
Abstract: Dimethylphenylphosphine was used to efficiently initiate the thiol-Michael addition polymerization to yield 5-hydroxymethylfurfural (HMF) derivative based poly(β-thioether esters) with relatively high molecular weights (over 10 000 g mol−1) under mild conditions. The synthesized linear polymers with… read more here.
Keywords: poly thioether; polymerization; derivative based; thiol michael ... See more keywords
Hydrolytically degradable poly(β-thioether ester ketal) thermosets via radical-mediated thiol–ene photopolymerization
Sign Up to like & getrecommendations! Published in 2019 at "Polymer Chemistry"
DOI: 10.1039/c9py01082c
Abstract: Poly(β-thioether ester ketal) networks are reported that undergo complete degradation with tuneable degradation profiles under acid and/or basic conditions. read more here.
Keywords: thioether ester; poly thioether; ester ketal; hydrolytically degradable ... See more keywords
Synthesis of Silane-Based Poly(thioether) via Successive Click Reaction and Their Applications in Ion Detection and Cell Imaging
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DOI: 10.3390/polym11081235
Abstract: A series of poly(thioether)s containing silicon atom with unconventional fluorescence were synthesized via successive thiol click reaction at room temperature. Although rigid π-conjugated structure did not exist in the polymer chain, the poly(thioether)s exhibited excellent… read more here.
Keywords: poly thioether; cell imaging; via successive; thioether ... See more keywords