The Cluster Polyazide Complexes: Synthesis, Crystal Structures, and 14N NMR Studies of [{Re3(μ-X)3}(N3)9]3- (X = Br or I).
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DOI: 10.1021/acs.inorgchem.2c01949
Abstract: Azide cluster complexes [{Re3(μ-Br)3}(N3)9]3- and [{Re3(μ-I)3}(N3)9]3- were obtained by reaction of Re3X9 (X = Br or I, respectively) with sodium azide in methanol. The complexes were crystallized as cesium salts of the compositions Cs3[{Re3(μ-Br)3}(N3)9]·H2O (1)… read more here.
Keywords: polyazide complexes; 14n nmr; cluster; complexes synthesis ... See more keywords