Synthesis of polycyclic aminal heterocycles via decarboxylative cyclisation of dipeptide derivatives.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc00167e
Abstract: An oxidative-decarboxylative intramolecular cyclisation of dipeptide derivatives is reported. This transformation is promoted by phenyl iodine(III) diacetate (PIDA) in combination with BF3·OEt2. The reaction gives access to a variety of valuable polycyclic N-heterocyclic scaffolds containing… read more here.
Keywords: cyclisation dipeptide; polycyclic aminal; synthesis polycyclic; dipeptide derivatives ... See more keywords