Pd(II)-Catalyzed Enantioselective Desymmetrization of Polycyclic Cyclohexenediones: Conjugate Addition versus Oxidative Heck.
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DOI: 10.1021/acs.orglett.9b03293
Abstract: Pd(II)-catalyzed desymmetrization of polycyclic cyclohexenediones has been achieved with high enantio- and diastereoselectivities. Up to five contiguous stereocenters are desymmetrized, while simultaneously, an additional stereocenter is created by the enantioselective conjugate addition. Surprisingly, the conjugate… read more here.
Keywords: addition; conjugate addition; oxidative heck; desymmetrization polycyclic ... See more keywords