Ion Transport and the True Transference Number in Nonaqueous Polyelectrolyte Solutions for Lithium Ion Batteries
Sign Up to like & getrecommendations! Published in 2019 at "ACS Central Science"
DOI: 10.1021/acscentsci.9b00406
Abstract: Nonaqueous polyelectrolyte solutions have been recently proposed as high Li+ transference number electrolytes for lithium ion batteries. However, the atomistic phenomena governing ion diffusion and migration in polyelectrolytes are poorly understood, particularly in nonaqueous solvents.… read more here.
Keywords: transport; transference; ion; polyelectrolyte solutions ... See more keywords
Dipole-driven interlude of mesomorphism in polyelectrolyte solutions
Sign Up to like & getrecommendations! Published in 2022 at "Proceedings of the National Academy of Sciences of the United States of America"
DOI: 10.1073/pnas.2204163119
Abstract: Significance Control of self-assembled structures of charged macromolecules in aqueous solutions is vital in myriads of natural phenomena. In the simplest situation, uniformly charged polyelectrolyte chains in electrolyte solutions are homogeneously distributed due to their… read more here.
Keywords: driven interlude; polyelectrolyte solutions; mesomorphism polyelectrolyte; interlude mesomorphism ... See more keywords
Macroscopic forces in inhomogeneous polyelectrolyte solutions.
Sign Up to like & getrecommendations! Published in 2022 at "Physical review. E"
DOI: 10.1103/physreve.107.024503
Abstract: In this paper, we present a self-consistent field theory of macroscopic forces in spatially inhomogeneous flexible chain polyelectrolyte solutions. We derive an analytical expression for a stress tensor which consists of three terms: isotropic hydrostatic… read more here.
Keywords: forces inhomogeneous; stress; inhomogeneous polyelectrolyte; polyelectrolyte solutions ... See more keywords