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Published in 2018 at "Macromolecules"
DOI: 10.1021/acs.macromol.7b01764
Abstract: Polymer glasses can be either ductile, undergoing yielding and necking, or brittle, suffering from crazing and brittle fracture. Until recently, there was no satisfactory molecular-level interpretation of these processes. In this work, carefully designed polystyrene…
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Keywords:
chain;
polymer glasses;
network key;
chain network ... See more keywords
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Published in 2022 at "Physical review letters"
DOI: 10.1103/physrevlett.129.127801
Abstract: Semiflexible polymer glasses (SPGs), including those formed by the recently synthesized semiflexible conjugated polymers, are expected to be brittle because classical formulas for their craze extension ratio λ_{craze} and fracture stretch λ_{frac} predict that systems…
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Keywords:
ductility semiflexible;
polymer glasses;
unexpected ductility;
semiflexible polymer ... See more keywords