Cationic polymerization of butadiene using a titanium tetrachloride—tert-butyl chloride catalytic system
Sign Up to like & getrecommendations! Published in 2018 at "Russian Chemical Bulletin"
DOI: 10.1007/s11172-018-2234-0
Abstract: Cationic polymerization of butadiene using a titanium tetrachloride—tert-butyl chloride catalytic system allows one to synthesize with high rates and yield fully soluble polybutadiene with controlled molecular characteristics. It was shown that the obtained cationic polybuta… read more here.
Keywords: cationic polymerization; using titanium; butadiene using; polymerization butadiene ... See more keywords
Stereospecific polymerization of 1,3-butadiene catalyzed by iron (III) Salen complexes combined with exogenous electron donor
Sign Up to like & getrecommendations! Published in 2021 at "Materials today communications"
DOI: 10.1016/j.mtcomm.2021.102068
Abstract: Abstract Iron Salen complexes varied with steric effect were designed and examined in polymerization of butadiene coupled with triphenylphosphate as electron donor. The results demonstrate they are able to serve as unique catalysts, yielding a… read more here.
Keywords: electron donor; polymerization butadiene; butadiene; salen complexes ... See more keywords
Novel Cobalt Dichloride Complexes with Hindered Diphenylphosphine Ligands: Synthesis, Characterization, and Behavior in the Polymerization of Butadiene
Sign Up to like & getrecommendations! Published in 2019 at "Molecules"
DOI: 10.3390/molecules24122308
Abstract: Two novel cobalt diphenylphosphine complexes were synthesized by reacting cobalt(II) chloride with tert-butyl(diphenyl)phosphine (PtBuPh2) and (S)-(+)neomenthyldiphenylphosphine [(S)-NMDPP]. The crystal structure of the former was determined by single-crystal X-ray diffraction studies. The two complexes were then… read more here.
Keywords: polymerization; novel cobalt; cobalt dichloride; butadiene ... See more keywords