Theoretical Investigations of Isoprene Polymerization Catalyzed by Cationic Half-Sandwich Scandium Complexes Bearing a Coordinative Side Arm
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DOI: 10.1021/acs.organomet.7b00876
Abstract: Density functional theory studies have been conducted for isoprene polymerization catalyzed by the cationic half-sandwich scandium alkyl species containing a methoxy side arm [(C5Me4C6H4OMe-o)Sc(CH2SiMe3)]+ (1) and that containing a phosphine oxide side arm [{C5Me4SiMe2CH2P(O)Ph2}Sc(CH2SiMe3)]+ (2).… read more here.
Keywords: side arm; polymerization catalyzed; isoprene polymerization; catalyzed cationic ... See more keywords
Theoretical insight on ethylene polymerization catalyzed by carborane-containing metal complexes: the role of carborane.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt03483d
Abstract: In this study, density functional theory calculations have been used to investigate the decisive role that the carborane (Cab) ligand plays in ethylene polymerization catalyzed by Cab-containing metal complexes. In the catalytic process, a large… read more here.
Keywords: containing metal; ethylene polymerization; metal; carborane ... See more keywords