Influences of Ligand Backbone Substituents on Phosphinecarbonylpalladium and -nickel Catalysts for Ethylene Polymerization and Copolymerization with Polar Monomers.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c01490
Abstract: A series of phosphinecarbonylpalladium and -nickel catalysts bearing various substituents on the ligand backbone were prepared, characterized, and used in ethylene polymerization and copolymerization with polar monomers. The Pd and Ni catalysts can achieve high… read more here.
Keywords: polymerization copolymerization; polymerization; ethylene polymerization; ligand backbone ... See more keywords
Harnessing data and control with AI/ML-driven polymerization and copolymerization.
Sign Up to like & getrecommendations! Published in 2025 at "Faraday discussions"
DOI: 10.1039/d5fd00066a
Abstract: Creating and curating new data to augment heuristics is a forthcoming approach to materials science in the future. Highly improved properties are advantageous even with "commodity polymers" that do not need to undergo new synthesis,… read more here.
Keywords: polymerization copolymerization; data control; harnessing data; copolymerization ... See more keywords
Ortho-Functionalized Dibenzhydryl Substituents in α-Diimine Pd Catalyzed Ethylene Polymerization and Copolymerization
Sign Up to like & getrecommendations! Published in 2020 at "Polymers"
DOI: 10.3390/polym12112509
Abstract: Sterically bulky diarylmethyl-based ligands have received increasing attention in the field of late-transition-metal catalyzed olefin polymerization. Ortho-substituents may have a significant impact on the performance of diarylmethyl-based α-diimine Pd catalysts. In this contribution, a series… read more here.
Keywords: polymerization copolymerization; polymerization; catalysts bearing; functionalized dibenzhydryl ... See more keywords