Effect of AlEt2Cl on the polymerization of isoprene using TiCl4/MgCl2 type Ziegler-Natta catalyst: A DFT study
Sign Up to like & getrecommendations! Published in 2021 at "Molecular Catalysis"
DOI: 10.1016/j.mcat.2021.111399
Abstract: Abstract Alkylaluminium is one of the components of the Ziegler-Natta catalysts, which plays a significant role in the active materials with different regions and stereoselectivity. The polymerization of isoprene with alkylaluminium in TiCl4/MgCl2 type Ziegler-Natta… read more here.
Keywords: polymerization isoprene; ziegler natta; mgcl2;
3,4-Enhanced Polymerization of Isoprene Catalyzed by Side-Arm Tridentate Iminopyridine Iron Complex with High Activity: Optimization via Response Surface Methodology
Sign Up to like & getrecommendations! Published in 2023 at "Polymers"
DOI: 10.3390/polym15051231
Abstract: 3,4-Enhanced polymerization of isoprene catalyzed by late transition metal with high activity remains one of the great challenges in synthetic rubber chemistry. Herein, a library of [N, N, X] tridentate iminopyridine iron chloride pre-catalysts (Fe… read more here.
Keywords: methodology; polymerization isoprene; activity; enhanced polymerization ... See more keywords