Articles with "polymerization kinetics" as a keyword



Regulation of Polymerization Kinetics to Improve Crystallinity of Carbon Nitride for Photocatalytic Reactions.

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Published in 2023 at "ChemSusChem"

DOI: 10.1002/cssc.202300361

Abstract: Carbon nitride (CN) polymers exhibit tunable and fascinating physicochemical properties and are thus an essential class of photocatalytic materials with potential applications. Although significant progress has been made in the fabrication of CN, the preparation… read more here.

Keywords: polymerization kinetics; regulation polymerization; carbon nitride; polymerization ... See more keywords

Delayed photo-activation and addition of thio-urethane: Impact on polymerization kinetics and stress of dual-cured resin cements.

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Published in 2017 at "Journal of dentistry"

DOI: 10.1016/j.jdent.2017.07.014

Abstract: OBJECTIVE 1) to determine the moment during the redox polymerization reaction of dual cure cements at which to photo-activate the material in order to reduce the polymerization stress, and 2) to evaluate possible synergistic effects… read more here.

Keywords: delayed photo; polymerization; polymerization kinetics; addition ... See more keywords
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Steric and Solvation Effects on Polymerization Kinetics, Dormancy, and Tacticity of Zr-Salan Catalysts

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Published in 2017 at "Organometallics"

DOI: 10.1021/acs.organomet.7b00295

Abstract: 1-Hexene polymerization using four zirconium-based amine bis(phenolate) catalysts, Zr[2-R-4-tBu-ONNO]Bn2 (where R = methyl (1), ethyl (2), isopropyl (3), and tert-butyl (4)), was examined to establish the effect of ligand sterics on kinetics and stereocontrol of… read more here.

Keywords: polymerization; polymerization kinetics; dormancy; steric solvation ... See more keywords

Comparison of the Macro Chain Transfer Agent and the Macro Azo Initiator Based on the Poly(3-hydroxy Butyrate) in the Polymerization Kinetics of Methyl Methacrylate

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Published in 2025 at "ACS Omega"

DOI: 10.1021/acsomega.4c08996

Abstract: Poly(3-hydroxybutyrate) (PHB) derivatives are attractive for sustainable polymer production, yet their role in controlling radical polymerization kinetics remains underexplored. In this study, we compare the polymerization kinetics of methyl methacrylate (MMA) using two PHB-based macroinitiators:… read more here.

Keywords: chain transfer; macro; raft; polymerization kinetics ... See more keywords

Direct hemoglobin S polymerization inhibitor MCP435 completely halts ongoing disease pathophysiology in transgenic sickle cell disease mice

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Published in 2025 at "Blood"

DOI: 10.1182/blood-2025-2932

Abstract: Background – Direct HbS polymerization inhibitors bind to the surface of Hemoglobin S and block polymerization by disrupting key surface residues involved in intermolecular interactions between HbS molecules in sickle fibers. MCP435, an analogue of… read more here.

Keywords: mice; disease; polymerization kinetics; polymerization ... See more keywords

Polymerization kinetics stability, volumetric changes, apatite precipitation, strontium release and fatigue of novel bone composites for vertebroplasty

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Published in 2019 at "PLoS ONE"

DOI: 10.1371/journal.pone.0207965

Abstract: Purpose The aim was to determine effects of diluent monomer and monocalcium phosphate monohydrate (MCPM) on polymerization kinetics and volumetric stability, apatite precipitation, strontium release and fatigue of novel dual-paste composites for vertebroplasty. Materials and… read more here.

Keywords: stability; strontium release; polymerization; polymerization kinetics ... See more keywords

Molecular Basis for Actin Polymerization Kinetics Modulated by Solution Crowding

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Published in 2023 at "Biomolecules"

DOI: 10.3390/biom13050786

Abstract: Actin polymerization drives cell movement and provides cells with structural integrity. Intracellular environments contain high concentrations of solutes, including organic compounds, macromolecules, and proteins. Macromolecular crowding has been shown to affect actin filament stability and… read more here.

Keywords: polymerization kinetics; actin; actin polymerization; solution crowding ... See more keywords

Comparative Effect of Self- or Dual-Curing on Polymerization Kinetics and Mechanical Properties in a Novel, Dental-Resin-Based Composite with Alkaline Filler. Running Title: Resin-Composites with Alkaline Fillers

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Published in 2018 at "Materials"

DOI: 10.3390/ma11010108

Abstract: Dental bulk-fill restorations with resin-composites (RBC) are increasing in popularity, but doubts concerning insufficient curing in depth still disconcert clinicians. An alternative might be offered by modern dual-cured RBCs, which additionally provide bioactive properties. This… read more here.

Keywords: resin; polymerization; polymerization kinetics; resin composites ... See more keywords

Polymerization Kinetics of Acrylic Photopolymer Loaded with Graphene-Based Nanomaterials for Additive Manufacturing

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Published in 2022 at "Nanomaterials"

DOI: 10.3390/nano12244498

Abstract: Graphene-based nanomaterials (GBN) can provide attractive properties to photocurable resins used in 3D printing technologies such as improved mechanical properties, electrical and thermal conductivity, and biological capabilities. However, the presence of GBN can affect the… read more here.

Keywords: graphene; based nanomaterials; polymerization kinetics; kinetics acrylic ... See more keywords

Blue Laser for Polymerization of Bulk-Fill Composites: Influence on Polymerization Kinetics

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Published in 2023 at "Nanomaterials"

DOI: 10.3390/nano13020303

Abstract: The objective of this study was to compare the polymerization kinetics of bulk-fill resin composites cured with a LED-curing device and a diode laser (449 nm). Three bulk-fill composites were light-cured with constant radiation exposure… read more here.

Keywords: fill composites; bulk fill; polymerization kinetics; polymerization ... See more keywords