Photolabile Well-Defined Polystyrene Grafted on Silica Nanoparticle via Nitroxide-Mediated Polymerization (NMP).
Sign Up to like & getrecommendations! Published in 2021 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202100181
Abstract: Herein, the synthesis of a novel nitroxide-mediated polymerization (NMP) initiator bearing a photolabile ortho-nitrobenzyl (oNB) group allowing surface-initiated NMP preparation of well-defined photoresponsive polystyrene grafted on silica nanoparticles is described. The photocleavable and photoresponsive properties… read more here.
Keywords: well defined; grafted silica; mediated polymerization; nitroxide mediated ... See more keywords
The Role of Nitroxide Degradation on the Efficiency of the Controller in Nitroxide-Mediated Radical Polymerization (NMP) of Styrene
Sign Up to like & getrecommendations! Published in 2020 at "Industrial & Engineering Chemistry Research"
DOI: 10.1021/acs.iecr.0c03547
Abstract: The effect of nitroxide degradation on polymerization rate and molar mass development in the nitroxide-mediated radical polymerization (NMP) of styrene is studied using electron spin resonance (ESR... read more here.
Keywords: polymerization; radical polymerization; nitroxide degradation; nitroxide mediated ... See more keywords