Tridentate diarylamido-based pincer complexes of nickel and palladium: sidearm effects in the polymerization of norbornene.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt02361e
Abstract: Nickel and palladium complexes bearing new diarylamido-based unsymmetrical [NNNox] and [SNNox] pincer ligands were synthesized and tested for the polymerization of norbornene. Upon the activation of MAO, all the palladium complexes showed high catalytic activities… read more here.
Keywords: diarylamido based; polymerization; nickel palladium; sidearm effects ... See more keywords
Catalytic performance of tridentate versus bidentate Co(ii) complexes supported by Schiff base ligands in vinyl addition polymerization of norbornene
Sign Up to like & getrecommendations! Published in 2022 at "RSC Advances"
DOI: 10.1039/d2ra07241f
Abstract: A series of Co(ii) complexes supported by Schiff base ligands, LA–LC, where LA, LB, and LC are (E)-3-methoxy-N-(quinolin-2-ylmethylene)propan-1-amine, (E)-N1,N1-dimethyl-N2-(pyridin-2-ylmethylene)ethane-1,2-diamine, and (E)-N1,N1-dimethyl-N2-(thiophen-2-ylmethylene)ethane-1,2-diamine, respectively, were designed and synthesized. Structural studies revealed a distorted trigonal bipyramidal geometry for… read more here.
Keywords: complexes supported; base ligands; geometry; polymerization norbornene ... See more keywords