Lewis Pair Polymerization of Renewable Indenone to Erythro-Ditactic High-Tg Polymers with an Upcycling Avenue
Sign Up to like & getrecommendations! Published in 2020 at "Macromolecules"
DOI: 10.1021/acs.macromol.9b02285
Abstract: Preparation and storage of biorenewable, monomeric indenone, much less the polymerization to a well-defined, high-molecular-weight polymer, is challenging because of antiaromaticity-driven radical autopolymerization. Herein, we report the successful preparation and subsequent Lewis pair polymerization (LPP)… read more here.
Keywords: polymerization renewable; polymerization; lewis pair; renewable indenone ... See more keywords
Rapid and Living Polymerization of Renewable Methylene Butyrolactones via Borane/Phosphine Lewis Pairs
Sign Up to like & getrecommendations! Published in 2025 at "Polymer Chemistry"
DOI: 10.1039/d5py00789e
Abstract: Living polymerization techniques are crucial for polymer synthesis and applications. However, developing living/controlled polymerization systems for renewable monomers remains challenging. This study presents a highly effective organic Lewis pair system,... read more here.
Keywords: polymerization renewable; lewis; renewable methylene; polymerization ... See more keywords