Articles with "polymers intrinsic" as a keyword



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Characterization of microstructures and reaction mechanisms of Tröger's base polymers of intrinsic microporosity

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Published in 2020 at "Rapid Communications in Mass Spectrometry"

DOI: 10.1002/rcm.8713

Abstract: Rationale Troger's base polymers of intrinsic microporosity (PIMs) are receiving increasing attention for applications such as polymer molecular sieve membranes. Development of novel membrane materials requires microstructure analysis in order to overcome processing and applications… read more here.

Keywords: troger base; intrinsic microporosity; polymers intrinsic; base ... See more keywords
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Amidoxime Modified Polymers of Intrinsic Microporosity (PIM-1); A Versatile Adsorbent for Efficient Removal of Charged Dyes; Equilibrium, Kinetic and Thermodynamic Studies

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Published in 2020 at "Journal of Polymers and the Environment"

DOI: 10.1007/s10924-020-01664-4

Abstract: Abstract Polymers of Intrinsic Microporosity (PIMs) are recognized as promising polymers for active separation of organic pollutants. These highly porous and solution-processable polymers could be tailored to remove specific targets from an aqueous system. In… read more here.

Keywords: adsorption; pim; intrinsic microporosity; amidoxime pim ... See more keywords
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Mixed matrix membranes comprising polymers of intrinsic microporosity and covalent organic framework for gas separation

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Published in 2017 at "Journal of Membrane Science"

DOI: 10.1016/j.memsci.2017.01.042

Abstract: Abstract Polymers of intrinsic microporosity (PIMs) exhibit the inherent superior permeability over traditional commercial polymers, however, the relatively low selectivity restrict their broad application in gas separation. In this study, novel kinds of mixed matrix… read more here.

Keywords: microporosity; polymers intrinsic; gas separation; intrinsic microporosity ... See more keywords
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Enhanced CO2 selectivities by incorporating CO2-philic PEG-POSS into Polymers of Intrinsic Microporosity membrane

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Published in 2017 at "Journal of Membrane Science"

DOI: 10.1016/j.memsci.2017.08.050

Abstract: Abstract The urgent demand of capturing CO 2 from energy relevant applications stimulated researchers to develop novel high-performance membrane materials. PIM-1, a representative class of polymers of intrinsic microporosity (PIMs), possesses high permeability but low… read more here.

Keywords: peg poss; intrinsic microporosity; polymers intrinsic; membrane ... See more keywords
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Thin film composite membranes from polymers of intrinsic microporosity using layer-by-layer method

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Published in 2019 at "Journal of Membrane Science"

DOI: 10.1016/j.memsci.2018.11.028

Abstract: Abstract There is a clear need for developing novel membrane chemistries to address industrial separation needs and improve the energy efficiency. Polymers with intrinsic microporosity (PIMs) are a novel class of polymers for which the… read more here.

Keywords: intrinsic microporosity; thin film; layer; polymers intrinsic ... See more keywords
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Soluble polymers with intrinsic porosity for efficient removal of phenolic compounds from water

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Published in 2021 at "Microporous and Mesoporous Materials"

DOI: 10.1016/j.micromeso.2021.111068

Abstract: Abstract Adsorbents have been a long-standing territory of insoluble solid materials in the field of adsorption technique for organic pollutants removal from wastewater. While the robust porous frameworks with high surface areas can give high… read more here.

Keywords: water; porosity efficient; intrinsic porosity; water soluble ... See more keywords
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BODIPY-Based Polymers of Intrinsic Microporosity for the Photocatalytic Detoxification of a Chemical Threat.

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Published in 2022 at "ACS applied materials & interfaces"

DOI: 10.1021/acsami.1c21750

Abstract: Effective heterogeneous photocatalysts capable of detoxifying chemical threats in practical settings must exhibit outstanding device integrity. We report a copolymerization that yields robust, porous, processible, chromophoric BODIPY (BDP; boron-dipyrromethene)-containing polymers of intrinsic microporosity (BDP-PIMs). Installation… read more here.

Keywords: bdp; polymers intrinsic; triplet; chemical ... See more keywords
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Adjustable Functionalization of Hyper-Cross-Linked Polymers of Intrinsic Microporosity for Enhanced CO2 Adsorption and Selectivity over N2 and CH4

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Published in 2022 at "ACS Applied Materials & Interfaces"

DOI: 10.1021/acsami.2c02604

Abstract: In this paper, we report the design, synthesis, and characterization of a series of hyper-cross-linked polymers of intrinsic microporosity (PIMs), with high CO2 uptake and good CO2/N2 and CO2/CH4 selectivity, which makes them competitive for… read more here.

Keywords: adsorption; cross linked; linked polymers; selectivity ... See more keywords
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Polymers with intrinsic microporosity chemical sorbents utilizing primary amine appendance through acid-base and hydrogen bonding interactions.

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Published in 2019 at "ACS applied materials & interfaces"

DOI: 10.1021/acsami.9b09856

Abstract: Here we present novel chemical sorbents based on polymers with intrinsic microporosity (PIM). For the first time, alkyl amines were incorporated in PIMs through an acid-base interaction to create a chemi-sorbent. The amine-appended PIM polymers… read more here.

Keywords: polymers intrinsic; chemical sorbents; acid base; intrinsic microporosity ... See more keywords
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Palladium catalyst imbedded in polymers of intrinsic microporosity for the Suzuki–Miyaura coupling reaction

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Published in 2018 at "RSC Advances"

DOI: 10.1039/c8ra06214e

Abstract: Polymers of intrinsic microporosity (PIMs) are porous polymers with rigid ladder-type chain structures. Synthesizing these polymers usually involves the step polymerization of two types of monomer, namely, active fluorine-substituted aromatic ring monomers and phenolic monomers.… read more here.

Keywords: miyaura coupling; coupling reaction; intrinsic microporosity; polymers intrinsic ... See more keywords
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An artificial solid interphase with polymers of intrinsic microporosity for highly stable Li metal anodes.

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Published in 2019 at "Chemical communications"

DOI: 10.1039/c9cc01329f

Abstract: Polymers of intrinsic microporosity (PIM-1) have an appropriate pore size to reduce the solvation number of Li ions in electrolytes. This unique pore structure of PIM-1 as a solid interphase can suppress transport of solvent… read more here.

Keywords: metal anodes; polymers intrinsic; solid interphase; intrinsic microporosity ... See more keywords