Pentazolate coordination polymers self-assembled by in situ generated [Pb4(OH)4]4+ cubic cations trapping cyclo-N5.
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DOI: 10.1039/d1dt04392g
Abstract: A series of cyclo-N5--based lead-containing energetic coordination polymers [Pb(OH)]4(N5)4 (1), [Pb3(N5)3(H2O)9(NO3)]4(N5)8(H2O)5 (2), [Pb(OH)]4(N5)3(NO3)(H2O)3 (3), and [Pb(OH)]4(N5)3(ClO4)(H2O) (4) were synthesized by self-assembly and characterized by single-crystal X-ray diffraction, powder X-ray diffraction, infrared and Raman spectroscopy, high… read more here.
Keywords: coordination; polymers self; cyclo; self assembled ... See more keywords