Iridium-induced regioselective B-H and C-H activations at azo-substituted m-carboranes: facile access to polynuclear complexes.
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DOI: 10.1039/c8cc09084j
Abstract: Iridium(iii)-induced selective B(2,3)-H and C-H bond activations at mono- and bi-p-methoxybenzeneazo-substituted m-carboranes have been investigated. A powerful methodology is introduced for the preparation of unique polynuclear complexes featuring m-carboranyl ligands in a single step. The… read more here.
Keywords: polynuclear complexes; induced regioselective; substituted carboranes; iridium induced ... See more keywords
Synthesis, X-ray structures, and magnetic properties of seven polynuclear Cu(II) complexes containing pyrazole-3,5-dicarboxylate with various ancillary ligands
Sign Up to like & getrecommendations! Published in 2023 at "New Journal of Chemistry"
DOI: 10.1039/d3nj00821e
Abstract: A series of polynuclear Cu(II) complexes, namely, (Him)2[Cu2(pzdc)2(H2O)2] (1), [Cu3(pzdc)2(im)2(H2O)4] (2), {[Na4Cu4(pzdc)4(im)4(H2O)2]·16H2O}n (3), (Hamp)2[Cu2(pzdc)2(H2O)2] (4), (H2tmdp)2[Cu4(pzdc)4(H2O)2]·2H2O (5), {[Cu2(pzdc)2][Cu(H2O)6]}n (6), and [Cu3(pzdc)2(en)2(H2O)2]n (7) were successfully synthesized under the reaction of Cu(NO3)2∙3H2O,... read more here.
Keywords: pzdc h2o; synthesis ray; cu2 pzdc; pzdc ... See more keywords