Structural diversity of polynuclear MgxOy cores in magnesium phenoxide complexes.
Sign Up to like & getrecommendations! Published in 2017 at "Acta crystallographica. Section C, Structural chemistry"
DOI: 10.1107/s2053229617012657
Abstract: The binuclear complex bis(2,6-di-tert-butyl-4-methylphenolato)-1κO,2κO-(1,2-dimethoxyethane-1κ2O,O')bis(μ-phenylmethanolato-1:2κ2O:O)(tetrahydrofuran-2κO)dimagnesium(II), [Mg2(C7H7O)2(C15H23O)2(C4H8O)(C4H10O2)] or [(BHT)(DME)Mg(μ-OBn)2Mg(THF)(BHT)], (I), was obtained from the complex [(BHT)Mg(μ-OBn)(THF)]2 by substitution of one tetrahydrofuran (THF) molecule with 1,2-dimethoxyethane (DME) in toluene (BHT is O-2,6-tBu2-4-MeC6H4 and Bn is benzyl). The trinuclear… read more here.
Keywords: bht; thf; bis; methylphenolato ... See more keywords