Articles with "polyoxometalate" as a keyword



Polyoxometalate Aerogels Formed by Organofunctionalized Anderson Polyoxometalates as Low Molecular Weight Gelators

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Published in 2025 at "Advanced Materials Interfaces"

DOI: 10.1002/admi.202500597

Abstract: Polyoxometalate‐based aerogels, built through supramolecular interactions and metal coordination, have the potential to expand the field of smart materials. Here, the first example of the conversion of an Anderson‐polyoxometalate‐based organogel into a catalytically active aerogel… read more here.

Keywords: anderson; polyoxometalate based; polyoxometalate aerogels; polyoxometalate ... See more keywords

Combining Cost-Efficient Cellulose and Short-Chain Carboxylic Acid Production: The Polyoxometalate (POM)-Ionosolv Concept.

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Published in 2020 at "ChemPlusChem"

DOI: 10.1002/cplu.202000025

Abstract: Full cost-effective exploitation of all wood components is key to growing a commercially successful biorefining industry. An innovative process is reported that combines fractionation of lignocellulosic biomass using a low-cost ionic liquid (Ionosolv) and production… read more here.

Keywords: polyoxometalate; ionosolv; formic acid; pom ionosolv ... See more keywords

Introducing of a novel polyoxometalate-based organic–inorganic hybrid: Insights into electochemical property-photoactivity relationship

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Published in 2020 at "Journal of Materials Science: Materials in Electronics"

DOI: 10.1007/s10854-020-04886-3

Abstract: Herein a new visible photocatalyst by TiO 2 and nanosized polyoxometalate-based inorganic–organic hybrid material, NaH 8 [PDA] 3 [PW 9 Co 3 O 37 ]·13H 2 O (PDA =  p -phenylenediamine) (PDA-Co 3 W 9 ),… read more here.

Keywords: photoactivity; polyoxometalate; polyoxometalate based; pda ... See more keywords

Effects of Competitive Active-Site Ligand Binding on Proton- and Electron-Transfer Properties of the [Co4(H2O)2(PW9O34)2]10− Polyoxometalate Water Oxidation Catalyst

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Published in 2017 at "Journal of Cluster Science"

DOI: 10.1007/s10876-016-1135-3

Abstract: Abstract The polyoxometalate [Co4(L)2(PW9O34)2]10−, where L is typically H2O, (1) is a much-studied homogeneous water oxidation catalyst that facilitates the conversion of water to dioxygen through a mechanism that remains poorly understood due to difficulty… read more here.

Keywords: polyoxometalate; pw9o34; water; water oxidation ... See more keywords

Polyoxometalate-coupled graphene nanohybrid via gemini surfactants and its electrocatalytic property for nitrite

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Published in 2019 at "Applied Surface Science"

DOI: 10.1016/j.apsusc.2018.09.246

Abstract: Abstract A novel graphene oxide (GO)-polyoxometalate (POM) nanohybrid is prepared using gemini surfactants (Gem) as stabilizers for the first time. The electrostatic interactions, chemical structure, and morphology of this Gem-GO-POM nanohybrid are systematically characterized, which… read more here.

Keywords: pom nanohybrid; pom; gemini surfactants; polyoxometalate ... See more keywords

Enhancement in proton conductivity by blending poly(polyoxometalate)-b-poly(hexanoic acid) block copolymers with sulfonated polysulfone

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Published in 2020 at "International Journal of Hydrogen Energy"

DOI: 10.1016/j.ijhydene.2020.04.039

Abstract: Abstract Designing polymer chains which contain building blocks with well-defined dimension is an efficient method to induce microphase separation and regulate the ionic channels of polymer electrolyte membranes (PEMs). In this study, a Wells-Dawson-type polyoxometalate… read more here.

Keywords: polyoxometalate; sulfonated polysulfone; pom; poly ... See more keywords

A homogeneous Cu-based polyoxometalate coupled with mesoporous TiO2 for efficient photocatalytic H2 production.

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Published in 2020 at "Journal of colloid and interface science"

DOI: 10.1016/j.jcis.2020.11.018

Abstract: Developing a photocatalytic system for water splitting to H2 is a promising strategy to address fossil fuel consumption. Exploring photocatalysts with high-performance, steady and low-cost has been the essential goals toward photo-reduction of water. Herein,… read more here.

Keywords: tio2; polyoxometalate; production; meso tio2 ... See more keywords

Robust polyoxometalate-loaded nickel foam for electrocatalytic oxygen evolution reaction

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Published in 2018 at "Materials Letters"

DOI: 10.1016/j.matlet.2018.03.133

Abstract: Abstract A tetraruthenium-containing polyoxometalate has been immobilized on the commercial nickel foam electrode by a facile method and the electrocatalytic oxygen evolution activity has been investigated. The molecular structure of the polyoxoanion does not change… read more here.

Keywords: oxygen evolution; polyoxometalate; nickel foam; electrocatalytic oxygen ... See more keywords

A Preyssler-type polyoxometalate-based coordination supramolecule with proton conducting property

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Published in 2019 at "Polyhedron"

DOI: 10.1016/j.poly.2019.04.058

Abstract: Abstract Developing new low-cost and efficient proton-conducting materials remains an attractive and challenging task. Herein, a Preyssler-type polyoxometalate derived coordination compound had been synthesized with a hydrothermal method, namely, H4.5NaCo5(2-MI)15.5(2-MI)3 [NaP5W30O110]·5H2O (1) (where 2-methylimidazole is… read more here.

Keywords: type polyoxometalate; preyssler type; polyoxometalate; proton conducting ... See more keywords

Polyoxometalate intercalated La-doped NiFe-LDH for efficient removal of tetracycline via peroxymonosulfate activation

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Published in 2021 at "Separation and Purification Technology"

DOI: 10.1016/j.seppur.2021.119113

Abstract: Abstract In this work, a series of La-doped NiFe-layered double hydroxides containing a novel Keggin type polyoxometalate interlayer (NiFeLa{HPW}-LDH) were synthesized and initially applied as heterogeneous catalyst for peroxymonosulfate (PMS) activation. Characterizations indicated that polyoxometalate… read more here.

Keywords: activation; iii; iii iii; hpw ... See more keywords

Directing the Linkage of Small Polyoxometalate Building Blocks Using (Benzene)ruthenium Cations

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Published in 2024 at "Inorganic Chemistry"

DOI: 10.1021/acs.inorgchem.4c04150

Abstract: Oligomerization of monomeric molybdate and tungstate oxyanions in the presence of organometallic cations produces a group of organometallic-polyoxometalate clusters, which have diverse structures based on cubane-like {M4O4} units resembling the structure of oxide surfaces. This… read more here.

Keywords: c6h6; building blocks; polyoxometalate; polyoxometalate building ... See more keywords