Hepta-Zr-Incorporated Polyoxometalate Assembly.
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DOI: 10.1021/acs.inorgchem.2c01124
Abstract: Driven by the synergistic-directing effect of the lacunary fragments, [B-α-GeW9O34]10- and [B-α-GeW11O39]8-, an unprecedented hepta-Zr-substituted polyoxometalate (POM) assembly K2Na6H10(Hpy)3[SbZr7O6(OH)4(B-α-GeW9O34)2(B-α-GeW11O39)2]·28H2O (1) was made under hydrothermal condition and structurally characterized. Of which, a unique hepta-Zr cluster, [SbZr7O6(OH)4]15+… read more here.
Keywords: incorporated polyoxometalate; gew11o39; hepta; geometry ... See more keywords