The Ultra-Deep Desulfurization of Model Oil Using Amphipathic Lindqvist-Type Polyoxometalate-Based TiO2 Nanofibres as Catalysts
Sign Up to like & getrecommendations! Published in 2020 at "Catalysis Letters"
DOI: 10.1007/s10562-020-03432-4
Abstract: A new amphipathic lindqvist-type polyoxometalate-based TiO2 nanofibres catalysts (50-DTA-MoO-TiO2NF, DTA = CH3(CH2)11(CH3)3N, MoO = Mo6O192-, TiO2 NF = TiO2 nanofibres, the weight percentage of DTA-MoO was 50%) was obtained by electrospinning and applied in desulfurization… read more here.
Keywords: desulfurization; polyoxometalate based; type polyoxometalate; amphipathic lindqvist ... See more keywords
Introducing of a novel polyoxometalate-based organic–inorganic hybrid: Insights into electochemical property-photoactivity relationship
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Materials Science: Materials in Electronics"
DOI: 10.1007/s10854-020-04886-3
Abstract: Herein a new visible photocatalyst by TiO 2 and nanosized polyoxometalate-based inorganic–organic hybrid material, NaH 8 [PDA] 3 [PW 9 Co 3 O 37 ]·13H 2 O (PDA = p -phenylenediamine) (PDA-Co 3 W 9 ),… read more here.
Keywords: photoactivity; polyoxometalate; polyoxometalate based; pda ... See more keywords
A Novel Ag(I)-Containing Polyoxometalate-Based MOF for Visible-Light-Driven Water Oxidation
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Cluster Science"
DOI: 10.1007/s10876-019-01703-8
Abstract: A novel 3D Ag(I)-containing polyoxometalate-based MOF of H17[Ag9(AgH8W11O44)2(BPY)9]·2.5H2O (WAg–BPY; BPY = 4,4′-bipyridine) has been solvothermally synthesized, and structurally characterized by elemental analyses, IR spectrum, UV–Vis spectrum, powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction. WAg–BPY exhibits highly… read more here.
Keywords: polyoxometalate based; novel containing; wag bpy; containing polyoxometalate ... See more keywords
Polyoxometalate-based ionic liquid supported on graphite carbon induced solvent-free ultra-deep oxidative desulfurization of model fuels
Sign Up to like & getrecommendations! Published in 2017 at "Fuel"
DOI: 10.1016/j.fuel.2016.11.024
Abstract: A supported heterogeneous catalyst with polyoxometalate-based ionic liquid (POM-IL) [N-(3-sulfonatepropyl)-pyridinium]3PMo12O40 ([PSPy]PMo) served as active component was prepared and graphite carbon (GC) with layer structure was used as support. Characterizations of the supported catalyst by FT-IR,… read more here.
Keywords: ionic liquid; polyoxometalate based; graphite carbon; solvent free ... See more keywords
Polyoxometalate-based heteronuclear complexes [Fe 2 M 2 (H 2 O) 2 (FeW 9 O 34 ) 2 ] n− (M=Mn II , Mn III , Ni II ) prepared by a pH-controllable degradation approach
Sign Up to like & getrecommendations! Published in 2017 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2016.12.010
Abstract: Abstract Three new heteronuclear [FeW9O34]-based sandwich-type complexes [FeIII2MnII2(H2O)2(FeW9O34)2]12− (1), [FeIII2MnIII2(H2O)2(FeW9O34)2]10− (2) and [FeIII2NiII2(H2O)2(FeW9O34)2]12− (3) have been synthesized by an innovative method of pH-controllable degradation in aqueous solution, in which the [FeW12O40]5− precursor could be predominantly… read more here.
Keywords: polyoxometalate based; controllable degradation; heteronuclear complexes; h2o few9o34 ... See more keywords
Two Keggin polyoxometalate-based hybrid compounds with different helix: Syntheses, structure and catalytic activities
Sign Up to like & getrecommendations! Published in 2017 at "Polyhedron"
DOI: 10.1016/j.poly.2017.04.017
Abstract: Abstract By adjusting pH value, two new Keggin polyoxometalate-based hybrid compounds with different helical structure, [Ag6(btp)(pyttz)6·(HSiMo12O40)2]·4H2O (1) and [Ag2(pyttz)4·(H2SiMo12O40)2]·(TMA)2·4H2O (2), (pyttz = 3-(pyrid-4-yl)-5-(1 H-1,2,4–3-yl)-1,2,4-triazolyl, btp = 5,5′-di(pyridin-4-yl)-1 H,1′H-3,3′-bi(1,2,4-triazole), TMA = tetramethylammonium), were successfully isolated by hydrothermal reaction and structurally characterized. Structural analysis shows… read more here.
Keywords: polyoxometalate based; compounds different; catalytic activities; hybrid compounds ... See more keywords
Chelation-Assisted Selective Etching Construction of Hierarchical Polyoxometalate-Based Metal–Organic Framework
Sign Up to like & getrecommendations! Published in 2020 at "Chemistry of Materials"
DOI: 10.1021/acs.chemmater.0c00440
Abstract: A chelation-assisted selective etching (CASE) strategy is developed to construct a hierarchical polyoxometalate-based metal–organic framework (POM@MOF). The selected chelator, ethylenediaminetetraa... read more here.
Keywords: hierarchical polyoxometalate; polyoxometalate based; chelation assisted; assisted selective ... See more keywords
A Copper-Containing Polyoxometalate-Based Metal-Organic Framework as an Efficient Catalyst for Selective Catalytic Oxidation of Alkylbenzenes.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c03741
Abstract: A copper-containing polyoxometalate-based metal-organic framework (POMOF), CuI12Cl2(trz)8[HPW12O40] (HENU-7, HENU = Henan University; trz = 1,2,4-triazole), has been successfully synthesized and well-characterized. In addition, the excellent catalytic ability of HENU-7 has been proved by the selective… read more here.
Keywords: polyoxometalate based; oxidation; copper containing; metal ... See more keywords
Capped Keggin Type Polyoxometalate-Based Inorganic-Organic Hybrids Involving In Situ Ligand Transformation as Supercapacitors and Efficient Electrochemical Sensors for Detecting Cr(VI).
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03097
Abstract: To construct polyoxometalate-based complexes as electrode materials for supercapacitors and electrochemical sensors, we intentionally used in situ ligand transformation during the reaction. Two complexes based on polyoxometalates capped by zinc ions, H{Zn4(DIBA)4[(DIBA)(HPO2)]2(α-PMoVI8MoV4O40Zn2)} (1) and [ε-PMoV8MoVI4O37(OH)3Zn4(HDBIBA)2]·6H2O… read more here.
Keywords: ligand transformation; polyoxometalate based; efficient electrochemical; situ ligand ... See more keywords
Design of a Polyoxometalate-Based Metal-Organic Framework for Photocatalytic C(sp3)-H Oxidation of Toluene.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03150
Abstract: A powerful and promising route for developing novel photocatalysts for light-driven toluene oxidation in water under mild conditions is presented. Herein, a novel polyoxometalate-based metal-organic framework (POMOF), {Co4W22-DPNDI}, is prepared by incorporating the unusual Co4-sandwiched… read more here.
Keywords: oxidation; polyoxometalate based; framework; water ... See more keywords
Copper-Containing Polyoxometalate-Based Metal-Organic Framework as a Catalyst for the Oxidation of Silanes: Effective Cooperative Catalysis by Metal Sites and POM Precursor.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c03835
Abstract: The oxidation of silanes into silanols is a very necessary transformation, and yet the rational fabrication of efficient catalysts for this reaction remains a challenging task. Here, a 3D polyoxometalate-based metal-organic framework (POMOF), [CuΙ3(pz)3{PMo12O40}]·H2O (HENU-8,… read more here.
Keywords: oxidation; oxidation silanes; metal organic; polyoxometalate based ... See more keywords